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743003

Sigma-Aldrich

2-Butanone peroxide

technical

Sinónimos:

Ethyl methyl ketone peroxide, Methyl ethyl ketone peroxide

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About This Item

Fórmula lineal:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
Número de CAS:
1338-23-4
Peso molecular:
210.22
Beilstein/REAXYS Number:
1759757
MDL number:
MFCD00042641
UNSPSC Code:
12352120
PubChem Substance ID:
329765606
NACRES:
NA.22

grade

technical

form

liquid

contains

2,2,4-trimethyl-1,3-pentanediol-diisobutyrate as stabilizer

reaction suitability

reagent type: oxidant

refractive index

n20/D 1.432

density

1.053 g/mL at 20 °C (lit.)

storage temp.

2-8°C

SMILES string

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI key

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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Application

Reactant for:
  • Studies of the adiabatic runaway reaction of Me Et Ketone peroxide
  • Quantitation of metal ions in archaeological glass via abrasive stripping square-wave voltammetry
  • Imaging of hydrogen peroxide and hydrogen peroxide-scavenging substances by photon emission
  • Synthesis of oligonucleotides via phosphoramidite method
  • Oxidation of nucleoside phosphites into phosphates
  • Comparing the relative effectiveness of human plasma glutathione peroxidase as a catalyst for reduction of hydroperoxidases

Analyte for direct electrochemical catalystis of immobilized Hb in an ethanol-water mixture

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 3 - Org. Perox. D - Skin Corr. 1B

Storage Class

5.2 - Organic peroxides and self-reacting hazardous materials

wgk_germany

WGK 1

flash_point_f

132.8 °F - closed cup

flash_point_c

56 °C - closed cup

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Oesophageal stenosis in a child caused by ingestion of methyl ethyl ketone peroxide.
A Prez-Martnez et al.
European journal of pediatrics, 156(12), 976-977 (1998-02-07)
P J Karhunen et al.
Human & experimental toxicology, 9(3), 197-200 (1990-05-01)
Fatal massive peripheral zonal hepatic necrosis developed in a 47-year-old man who accidentally ingested a solution of methyl ethyl ketone peroxide (MEKP) in dimethyl phthalate. Such solutions contain about 10% active oxygen. The clinical course was characterized by temporary cardiac
M N Bozdemir et al.
Human & experimental toxicology, 30(12), 2002-2006 (2011-04-22)
Although ingestion of methyl ethyl ketone peroxide (MEKP) is rare, it carries a high risk of morbidity and mortality. This paper reports the first such case from Turkey in which a 70-year-old man unintentionally ingested MEKP in his kitchen. The
Jing Zhang et al.
Journal of hazardous materials, 181(1-3), 1024-1030 (2010-06-18)
Methyl ethyl ketone peroxide (MEKPO) is widely used in polymer industry. It is highly sensitive to heat, friction, shock, flame or other sources of ignition, causing risks in production, storage and transportation. In this article, MEKPO is synthesized at a
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and
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