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Sigma-Aldrich

Biphenyl-3,3′,5,5′-tetracarboxylic acid

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About This Item

Fórmula empírica (notación de Hill):
C16H10O8
Número de CAS:
4371-28-2
Peso molecular:
330.25
MDL number:
MFCD16621475
UNSPSC Code:
26111700
PubChem Substance ID:
329763808
NACRES:
NA.23

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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mp

>400 °C

greener alternative category

, Enabling

SMILES string

OC(=O)c1cc(cc(c1)-c2cc(cc(c2)C(O)=O)C(O)=O)C(O)=O

InChI

1S/C16H10O8/c17-13(18)9-1-7(2-10(5-9)14(19)20)8-3-11(15(21)22)6-12(4-8)16(23)24/h1-6H,(H,17,18)(H,19,20)(H,21,22)(H,23,24)

InChI key

QURGMSIQFRADOZ-UHFFFAOYSA-N

General description

Biphenyl-3,3′,5,5′-tetracarboxylic acid (H4BPTC) is a carboxylic ligand material, which has multiple co-ordinated sites, and the carboxyl groups lie in the position of 120° that extend in all the directions. It has a luminescent property with an emission band maximum at 405 nm.[1][2]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Selected Applications of MOFs in Sustainable Energy Technologies
Biphenyl-3,3′,5,5′-tetracarboxylic acid is used for fabricating CPF-1,Cu2(bptc)(H2O)2,MOF-501,MOF-502,MOF-505, NOTT-100, NOTT-400, NOTT-401, SNU-M11,SNU-M10 a highly symmetrical chiral Mg-based metal organic framework (MOF) with nanotubular channels. These are used for selective gas adsorption.[3][4][5][6][7]

pictograms

Environment
GHS09

signalword

Warning

hcodes

H400

Hazard Classifications

Aquatic Acute 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKBX3841V
MKBJ1636V
MKBM8323V
MKBC7658V
MKBC7658

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A new PtS-type heterometallic compound constructed from biphenyl-3, 3?, 5, 5?-tetracarboxylate: Synthesis, structure and luminescent property
Zhu L, et al.
Journal of Molecular Structure, 1067, 239-242 (2014)
Highly porous and robust scandium-based metal?organic frameworks for hydrogen storage.
Ibarra I A, et al.
Chemical Communications (Cambridge, England), 47(29), 8304-8306 (2011)
Highly selective CO2 capture in flexible 3D coordination polymer networks.
Choi H S and Suh M P
Angewandte Chemie (International Edition in English), 48(37), 6865-6869 (2009)
Two new Cd (II) coordination polymer based on Biphenyl-3, 3?, 5, 5?-tetracarboxylic acid
Tan J, et al.
Inorganic Chemistry Communications, 87, 36-39 (2018)
High capacity hydrogen adsorption in Cu (II) tetracarboxylate framework materials: the role of pore size, ligand functionalization, and exposed metal sites.
Lin X, et al.
Journal of the American Chemical Society, 131(6), 2159-2171 (2009)
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