697737

Tris-(8-hydroxyquinoline)aluminum

sublimed grade, 99.995% trace metals basis

• Sinónimos: Alq3, Aluminum 8-hydroxyquinolinate, Aluminum oxinate, Tris-(8-hydroxyquinolinato)aluminum
• Fórmula empírica (notación de Hill): C₂₇H₁₈AlN₃O₃
• Número de CAS: 2085-33-8
• Peso molecular: 459.43
• EC Number: 218-227-0
• MDL number: MFCD00191693
• UNSPSC Code: 12352103
• PubChem Substance ID: 329761948
• NACRES: NA.23

Propiedades

• grade: sublimed grade
• assay: 99.995% trace metals basis
• form: solid
• loss: 0.5 wt. % loss on heating, 332°C (typical, TGA)
• mp: >300 °C (lit.); 411 °C (DSC)
• λmax: 259 nm
• fluorescence: λ_ex 390 nm; λ_em 519 nm
• orbital energy: HOMO 5.8 eV ; LUMO 3.1 eV
• OLED device performance: ITO/MoO₃/NPD/Alq₃/BPhen/LiF/Al;
  • Color: green
  • Max. Luminance: 20000 Cd/m²
  • Max. EQE: 1.2 %
  • Turn-On Voltage: 2.8 V
  ; ITO/NPD/CBP:Ir(ppy)₃/BCP/Alq₃/Mg:Al;
  • Color: green
  • Max. Luminance: 100000 Cd/m²
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V
  ; ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq₃/LiF/Al;
  • Color: red
  • Max. Luminance: 24529 Cd/m²
  • Max. EQE: 17 %
  • Turn-On Voltage: 2.7 V
  ; ITO/NPD/TCTA/BCPO:Ir(ppy)₃ (7-8%)/BCP/Alq₃/LiF/Al;
  • Color: green
  • Max. Luminance: 207839 Cd/m²
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V
  ; ITO/m-MTDATA/NPD/TTPhPhB/Alq₃/LiF/Al;
  • Color: blue
  • Max. Luminance: 9100 Cd/m²
  • Max. EQE: 2.5 %
  • Turn-On Voltage: 3.2 V
• SMILES string: O([Al](Oc1cccc2cccnc12)Oc3cccc4cccnc34)c5cccc6cccnc56
• InChI: 1S/3C9H7NO.Al/c3*11-8-5-1-3-7-4-2-6-10-9(7)8;/h3*1-6,11H;/q;;;+3/p-3
• InChI key: TVIVIEFSHFOWTE-UHFFFAOYSA-K

Descripción

General description

Tris(8-hydroxyquinoline)aluminum(III)(Alq₃) is a key green-light emitting and electron transport material for OLEDs. A study reports the new crystalline phase d besides its, originally known, three other crystalline phases, α,β,γ. It exhibits excellent chemical stability and high luminescence efficiencies.

Application

Thin films of tris(8-hydroxyquinoline) aluminum (Alq₃) can be used for organic electroluminescent devices.

Key green-light emitting and electron transport material for OLEDs.

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves