566950
4-Bromobenzyl mercaptan
97%
Sinónimos:
(4-Bromophenyl)methanethiol, 4-Bromo-α-toluenethiol
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About This Item
Fórmula lineal:
BrC6H4CH2SH
Número de CAS:
Peso molecular:
203.10
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Productos recomendados
assay
97%
mp
27-31 °C (lit.)
functional group
bromo
thiol
SMILES string
SCc1ccc(Br)cc1
InChI
1S/C7H7BrS/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2
InChI key
CUCKXDPCCYHFMQ-UHFFFAOYSA-N
Application
4-Bromobenzyl mercaptan may be used to synthesize 4-bromotoluene via desulfurization with molybdenum hexacarbonyl [Mo(CO)6] in tetrahydrofuran.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Zhengyu Zhang et al.
Chemical research in toxicology, 33(7), 1761-1769 (2020-06-10)
Dioscorea bulbifera L. (DBL), a traditional Chinese medicine, is a well-known herb with hepatotoxicity, and the biochemical mechanisms of the toxic action remain unknown. Diosbulbin B (DSB), a major component of DBL, can induce severer liver injury which requires cytochrome
?Transition-metal promoted reactions. 12. Molybdenum hexacarbonyl-promoted reductive cleavage of the carbon-sulfur bond?
Luh YT and Wong SC
The Journal of Organic Chemistry, 50(25), 5413-5415 (1985)
Franziska Leipoldt et al.
Nature communications, 8(1), 1965-1965 (2017-12-08)
Metalloproteinase inhibitors often feature hydroxamate moieties to facilitate the chelation of metal ions in the catalytic center of target enzymes. Actinonin and matlystatins are potent metalloproteinase inhibitors that comprise rare N-hydroxy-2-pentyl-succinamic acid warheads. Here we report the identification and characterization of their biosynthetic
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