463965

(3aR-cis)-(+)-3,3a,8,8a-Tetrahydro-2H-indeno[1,2-d]oxazol-2-one

97%

• Fórmula empírica (notación de Hill): C₁₀H₉NO₂
• Número de CAS: 135969-65-2
• Peso molecular: 175.18
• MDL number: MFCD00674088
• UNSPSC Code: 12352005
• PubChem Substance ID: 24870124

Propiedades

• assay: 97%
• optical activity: [α]22/D +76°, c = 0.65 in ethyl acetate
• optical purity: ee: 99% (HPLC)
• mp: 203-209 °C (lit.)
• SMILES string: O=C1N[C@H]2[C@H](Cc3ccccc23)O1
• InChI: 1S/C10H9NO2/c12-10-11-9-7-4-2-1-3-6(7)5-8(9)13-10/h1-4,8-9H,5H2,(H,11,12)/t8-,9+/m0/s1
• InChI key: XWZLNPUWNUTPAU-DTWKUNHWSA-N

Descripción

Application

Versatile chiral auxiliary used in a variety of highly diastereoselective reactions such as Michael additions, Diels-Alder reactions, cyclopropanations, and allylations.

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves