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MilliporeSigma

463779

Sigma-Aldrich

Ruthenium(III) chloride hydrate

99.98% trace metals basis

Sinónimos:

Trichlororuthenium hydrate, Ruthenium trichloride

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About This Item

Fórmula lineal:
RuCl3 · xH2O
Número de CAS:
Peso molecular:
207.43 (anhydrous basis)
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de la sustancia en PubChem:
NACRES:
NA.23

Nivel de calidad

Ensayo

99.98% trace metals basis

Formulario

powder and chunks

idoneidad de la reacción

reagent type: catalyst
core: ruthenium

impurezas

≤250.0 ppm Trace Metal Analysis

cadena SMILES

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

Clave InChI

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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Descripción general

Ruthenium(III) chloride hydrate exhibits excellent catalytic activity, attributed to the redox properties of ruthenium suitable for fuel cells and other electrochemical devices. It has ability to facilitate charge transfer and exhibit photoactive behavior.

Aplicación

Ruthenium(III) chloride hydrate can be used:
  • As a precursor to prepare ultralow Ru loaded graphene aerogel that exhibits electrocatalytic performance in the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR).
  • As a dopant to prepare Ru-doped TiO2 electron transport layer for mesoscopic perovskite solar cell by spin-coating technique. This helps to enhance photoconversion efficiency and air stability.
  • To fabricate ultra-uniform Ru nanocluster catalyst via small-molecule self-assembly pyrolysis method. These catalysts exhibit excellent hydrogen evolution activity in Zinc air batteries under all pH conditions.

Otras notas

soluble form

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Código de clase de almacenamiento

8A - Combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Visite la Librería de documentos

Fujita, S.-I., et al.
J. Catal., 255, 95-95 (2004)
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)

Artículos

Hydrogen is one of the most important resources in providing food, fuel, and chemical products for our everyday life. Sustainable catalytic hydrogen production from bioethanol has gained significant attention in recent years due to globally diminishing fossil fuel supplies, which have necessitated the search for new chemical feedstocks.

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