431885

Dichlorobis(methyldiphenylphosphine)palladium(II)

97%

• Sinónimos: NSC 148042
• Fórmula lineal: [(C₆H₅)₂PCH₃]₂PdCl₂
• Número de CAS: 52611-08-2
• Peso molecular: 577.76
• MDL number: MFCD00216594
• UNSPSC Code: 12352300
• PubChem Substance ID: 24867052
• NACRES: NA.22

Propiedades

• assay: 97%
• form: solid
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• SMILES string: Cl[Pd]Cl.CP(c1ccccc1)c2ccccc2.CP(c3ccccc3)c4ccccc4
• InChI: 1S/2C13H13P.2ClH.Pd/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;;;/h2*2-11H,1H3;2*1H;/q;;;;+2/p-2
• InChI key: GTSFBKGHQLDFHU-UHFFFAOYSA-L

Descripción

Application

Catalyst for:

• Ullmann reactions (homocoupling reactions)
• Cross coupling reaction of tributyltin hydride with aryl iodides
• Double silylation, double carbonylation and cyclocarbonylation reactions

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves