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MilliporeSigma

379875

Sigma-Aldrich

[Pd(OAc)2]3

99.98% trace metals basis

Sinónimos:

Pd(OAc)2

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1 G
$190.95
5 G
$751.45

$190.95

Precio de catálogo$201.00Ahorre 5 %

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1 G
$190.95
5 G
$751.45

About This Item

Fórmula lineal:
Pd(OCOCH3)2
Número de CAS:
Peso molecular:
224.51
Beilstein/REAXYS Number:
6086766
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

$190.95

Precio de catálogo$201.00Ahorre 5 %

En stockDetalles


Solicitar un pedido a granel

Quality Level

assay

99.98% trace metals basis

form

powder

reaction suitability

core: aluminum
reagent type: catalyst

mp

216.3-223.7 °C (dec.)

SMILES string

CC(O[Pd]OC(C)=O)=O

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

YJVFFLUZDVXJQI-UHFFFAOYSA-L

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Application

A non-halogenated palladium(II) complex. It has been used as a catalyst for coupling reactions[1] and as a precursor to prepare palladium-containing materials for heterogeneous catalysis.[2][3]

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Visite la Librería de documentos

Jujjuri, S.; et al.
J. Catal., 239 (2), 486-500 (2006)
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 53(44), 11895-11899 (2014-09-11)
A palladium-catalyzed dehydrogenative coupling between diarylamines and olefins has been discovered for the synthesis of substituted indoles. This intermolecular annulation approach incorporates readily available olefins for the first time and obviates the need of any additional directing group. An ortho palladation
Xu, J.; et al.
Journal of Nanoparticle Research, 7 (4-5), 449-467 (2005)
Hu Kang et al.
Journal of the American Chemical Society, 128(18), 6194-6205 (2006-05-04)
A novel type of "X-shaped" two-dimensional electro-optic (EO) chromophore with extended conjugation has been synthesized and characterized. This chromophore is found to exhibit a remarkably blue-shifted optical maximum (357 nm in CH(2)Cl(2)) while maintaining a very large first hyperpolarizability (beta).
Palladium-catalyzed synthesis of benzofurans and coumarins from phenols and olefins.
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 52(48), 12669-12673 (2013-10-16)

Questions

1–4 of 4 Questions  
  1. What is the solubility of Product 379875, Palladium (II) acetate?

    1 answer
    1. It is soluble in chloroform and acetone.  It will decompose in hydrochloric acid.  It is insoluble in water.

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  2. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  3. What is the melting point of Product 379875, Palladium (II) acetate?

    1 answer
    1. The melting point of this product is approximately 680 deg C.

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  4. Is Product 379875, Palladium (II) acetate, really 99.98% pure?

    1 answer
    1. The purity of 99.98% is not the actual chemical purity, but rather the purity based on trace metal content.  A maximum of 300ppm total metallic impurities would be allowed.

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