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Sigma-Aldrich

Fluorotrimethylsilane

96%

Sinónimos:

Trimethylfluorosilane, Trimethylsilyl fluoride

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About This Item

Fórmula lineal:
(CH3)3SiF
Número de CAS:
420-56-4
Peso molecular:
92.19
Beilstein/REAXYS Number:
1731132
EC Number:
206-997-0
MDL number:
MFCD00042064
UNSPSC Code:
12142100
PubChem Substance ID:
24862438

assay

96%

bp

16 °C (lit.)

mp

−74 °C (lit.)

density

0.793 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)F

InChI

1S/C3H9FSi/c1-5(2,3)4/h1-3H3

InChI key

CTIKAHQFRQTTAY-UHFFFAOYSA-N

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Packaging

Supplied in a Sure/Pac™ cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 1 - Press. Gas Compr. Gas - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

2A - Gases

wgk_germany

WGK 3

flash_point_f

-22.0 °F - closed cup

flash_point_c

-30 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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L G Hutchins et al.
The International journal of applied radiation and isotopes, 36(5), 375-378 (1985-05-01)
18F-Labeled fluorotrimethylsilane was prepared by nucleophilic substitution of chlorotrimethylsilane with reactor produced [18F]fluoride. Hydrolysis of fluorotrimethylsilane by aqueous tetraethylammonium hydroxide followed by removal of water with a mechanical pump gave a powerful source of no carrier added nucleophilic 18F. Reaction
[Gas chromatographic fluoride determination following adsorption of trimethylfluorsilane on Porapak P].
K Seifert
Zeitschrift fur die gesamte Hygiene und ihre Grenzgebiete, 29(2), 80-80 (1983-02-01)
M S Rosenthal et al.
The International journal of applied radiation and isotopes, 36(4), 318-319 (1985-04-01)
[18F]Fluorotrimethylsilane was prepared in 80% decay corrected yield by reaction of no-carrier added tetramethyl-ammonium fluoride (hydroxide as bulk anion) with chlorotrimethylsilane in 65% aqueous acetonitrile. The 18F gas was collected in a cold-trap at -130 degrees C and found to
P Venkateswarlu
Analytical chemistry, 64(4), 346-349 (1992-02-15)
The conventional procedure for separation of fluoride as trimethylfluorosilane in Conway diffusion cells involves the use of grease for sealing the cell and also for closing the hole in the lid drilled for introduction of hexamethyldisiloxane. We have developed a
S J Gatley
International journal of radiation applications and instrumentation. Part A, Applied radiation and isotopes, 40(6), 541-544 (1989-01-01)
A flow-through system is described for rapid purification of [18F]fluoride for nucleophilic substitution reactions. It depends on generation of [18F]fluorotrimethylsilane from aqueous 18F solutions and subsequent collection of the gas and its hydrolysis by base in near anhydrous acetonitrile. Potassium
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