344079

(+)-(S)-N,N-Dimethyl-1-[(R)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine

95%

• Fórmula empírica (notación de Hill): C₃₈H₃₇FeNP₂
• Número de CAS: 55650-59-4
• Peso molecular: 625.50
• MDL number: MFCD00075283
• UNSPSC Code: 12352005
• PubChem Substance ID: 24861222
• NACRES: NA.22

Propiedades

• assay: 95%
• optical activity: [α]20/D +350°, c = 0.5 in chloroform
• mp: 138-142 °C (lit.)
• SMILES string: [Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.C[C@@H]([C]4[CH][CH][CH][C]4P(c5ccccc5)c6ccccc6)N(C)C
• InChI: 1S/C21H23NP.C17H14P.Fe/c1-17(22(2)3)20-15-10-16-21(20)23(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h4-17H,1-3H3;1-14H;/t17-;;/m0../s1
• InChI key: VUJPTJYMSBMZOZ-RMRYJAPISA-N

Descripción

Application

Ligand used in the asymmetric hydrogenation of (Z)-α-amido-cinnamic acids

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H302 + H312 + H332,H315,H319,H335
• pcodes: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves