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MilliporeSigma

333395

Sigma-Aldrich

Dichlorosilane

≥99.99% trace metals basis

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About This Item

Fórmula lineal:
Cl2SiH2
Número de CAS:
Peso molecular:
101.01
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

vapor density

3.5 (vs air)

vapor pressure

1254 mmHg ( 20 °C)

description

film resistivity > 50 Ω-cm

assay

≥99.99% trace metals basis

autoignition temp.

136 °F

expl. lim.

99 %

bp

8.3 °C (lit.)

mp

−122 °C (lit.)

SMILES string

Cl[SiH2]Cl

InChI

1S/Cl2H2Si/c1-3-2/h3H2

InChI key

MROCJMGDEKINLD-UHFFFAOYSA-N

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General description

Dichlorosilane (DCS) is a halogenated silicon based precursor that facilitates the growth of a variety of silane based films such as silicon oxide, silicon nitride, silicon carbide, and epitaxial growth of silica.[1][2][3][4]

Application

DCS is widely used in the synthesis of a variety of silicon-based materials, which find applications in the development of organic electronics based devices, including OFETs, MEMS, NEMS, MOSFETS, and lithium-ion batteries.[3][4][5][6]

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Eye Dam. 1 - Flam. Gas 1 - Press. Gas Liquefied gas - Skin Corr. 1B

supp_hazards

Storage Class

2A - Gases

wgk_germany

WGK 1

flash_point_f

-34.6 °F

flash_point_c

-37 °C

ppe

Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)


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Paul A Jean et al.
Inhalation toxicology, 18(8), 515-522 (2006-05-24)
The acute inhalation toxicity of 10 chlorosilanes was investigated in Fischer 344 rats using a 1-h whole-body vapor inhalation exposure and a 14-day recovery period. The median lethal concentration (LC50(1)) for each material was calculated from the nominal exposure concentrations
High growth rate 4H−SiC epitaxial growth using dichlorosilane in a hot-wall CVD reactor.
Chowdhury I, et al.
Journal of Crystal Growth, 316(1), 60-66 (2011)
Low temperature-low hydrogen content silicon nitrides thin films deposited by PECVD using dichlorosilane and ammonia mixtures.
Santana G, et al.
Journal of Non-Crystalline Solids, 351(10-11), 922-928 (2005)
H Nakashima et al.
Archives of toxicology, 70(3-4), 218-223 (1996-01-01)
Using male ICR mice, the LC50 and acute and subacute inhalation toxicity of dichlorosilane (SiH2Cl2, DCS) and the fate of DCS released into the air were investigated. DCS resolved and minute particles including silicon and chloride were observed, when DCS
T Chen et al.
Electrophoresis, 20(12), 2412-2419 (1999-09-28)
The feasibility of polymeric phases based on a silicone polymer backbone as pseudostationary phases for electrokinetic chromatography has been investigated. Silicone phases were studied because of the range of chemistries that could be developed based on these backbones, and because

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