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291161

Sigma-Aldrich

4,7,13,16,21-Pentaoxa-1,10-diazabicyclo[8.8.5]tricosane

98%

Sinónimos:

Kryptofix® 221

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About This Item

Fórmula empírica (notación de Hill):
C16H32N2O5
Número de CAS:
31364-42-8
Peso molecular:
332.44
Beilstein/REAXYS Number:
616444
EC Number:
250-592-1
MDL number:
MFCD00005108
UNSPSC Code:
12352005
PubChem Substance ID:
24857516
NACRES:
NA.22

assay

98%

refractive index

n20/D 1.5018 (lit.)

density

1.111 g/mL at 20 °C (lit.)

SMILES string

C1COCCN2CCOCCOCCN(CCO1)CCOCC2

InChI

1S/C16H32N2O5/c1-7-19-8-2-18-5-11-22-15-13-20-9-3-17(1)4-10-21-14-16-23-12-6-18/h1-16H2

InChI key

HDLXPNDSLDLJHF-UHFFFAOYSA-N

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Application

4,7,13,16,21-Pentaoxa-1,10-diazabicyclo[8.8.5]tricosane is a cryptand which is capable of forming complexes with metal cations. It is used to bind or trap cationic guests such as Na+, Cd2+, Zn2+ and Eu3+.

Legal Information

Kryptofix is a registered trademark of Merck KGaA, Darmstadt, Germany

For use with

Referencia del producto
Descripción
Precios

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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R P Taylor et al.
Clinical biochemistry, 29(1), 33-37 (1996-02-01)
To develop methods based on enzyme activation for the analysis of sweat sodium and chloride using beta-galactosidase and alpha-amylase, respectively. Both were monitored kinetically on the Cobas Fara centrifugal analyzer. The sweat, collected with the Macroduct system, was diluted no
M Castaing et al.
The Journal of membrane biology, 97(2), 79-95 (1987-01-01)
The kinetics of Na+ and K+ transport across the membrane of large unilamellar vesicles (LUV) were determined at two pH's when transport was induced by (221)C10-cryptand (diaza-1,10-decyl-5-pentaoxa-4,7,13,16,21-bicyclo [8.8.5.] tricosane) at various temperatures, and by nonactin at 25 degrees C and
Amidinium carboxylate salt bridges as a recognition motif for mechanically interlocked molecules: synthesis of an optically active [2] catenane and control of its structure.
Nakatani Y, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 122(32), 5595-5599 (2010)
A Loiseau et al.
Biochimica et biophysica acta, 1235(1), 21-32 (1995-04-12)
The kinetics of the competitive transport of Na+ and K+ ions across the membrane of large unilamellar vesicles (LUV) were determined when transport was induced by (221)C10-cryptand, an ionizable mobile carrier. The experiments were performed at various pH values (7.7
Formation of Cadmium (II) Nitrate Complexes with Macrocycles.
Hak-Jin J and Oh-Jin J
Bull. Korean Chem. Soc., 14(5), 561-567 (1993)
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