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MilliporeSigma

224839

Sigma-Aldrich

Bismuth(III) chloride

reagent grade, ≥98%

Sinónimos:

Bismuth trichloride, Trichlorobismuth

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25 G
$125.00
100 G
$351.00
500 G
$1,250.00

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25 G
$125.00
100 G
$351.00
500 G
$1,250.00

About This Item

Fórmula empírica (notación de Hill):
BiCl3
Número de CAS:
Peso molecular:
315.34
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de la sustancia en PubChem:
NACRES:
NA.21

$125.00


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grado

reagent grade

Nivel de calidad

Ensayo

≥98%

Formulario

powder, chunks or granules

idoneidad de la reacción

reagent type: catalyst
core: bismuth

bp

447 °C (lit.)

mp

230-232 °C (lit.)

cadena SMILES

Cl[Bi](Cl)Cl

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3

Clave InChI

JHXKRIRFYBPWGE-UHFFFAOYSA-K

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Descripción general

Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine. [1]

Aplicación

Bismuth(III) chloride may be used as a catalyst in the following processes:
  • Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols.[2]
  • Preparation of thiiranes from oxiranes using ammonium thiocyanate.[3]
  • Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates.[4]
  • Allylation of secondary benzyl alcohols with allyltrimethylsilane.[5]
  • [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles.[6]

Pictogramas

Exclamation mark

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Eye Irrit. 2 - Skin Irrit. 2

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves


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Certificados de análisis (COA)

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Daintith J
The facts on file dictionary of chemistry, 28-28 (2014)
Bismuth (III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane
De SK & Gibbs RA.
Tetrahedron Letters, 46(48), 8345-8350 (2005)
Bismuth (III) chloride (BiCl3)-An efficient catalyst for mild, regio-and stereoselective cleavage of epoxides with alcohols, acetic Acid and water.
Mohammadpoor-Baltork I.
Synthetic Communications, 30(13), 2365-2374 (2000)
Bismuth (iii) Chloride Mediated Michaelis-Arbuzov Reaction: A Facile Synthesis of Substituted Arylphosphonates/Phosphinates and Bioactivity Evaluation.
Subramanyam C, et al.
Phosph. Sulfur Relat. Elem. (2015)
Bismuth (III) Chloride-Catalyzed Three-Component Coupling: Synthesis of a-Amino Phosphonates.
Zhan ZP and Li JP.
Synthetic Communications, 35(19), 2501-2508 (2005)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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