Journal of hazardous materials, 186(2-3), 1652-1659 (2011-01-11)
The aim of this work was to evaluate the efficiency of three chemical oxidation processes for increasing the biodegradability of aqueous diethanolamine solutions (aqueous DEA solutions), to be used as pre-treatments before a biological process. The raw aqueous DEA solution
The utility of propargyl diethanolamine boronates as reagents for the preparation of allenes and homopropargylic alcohols is presented. Protonolysis with TFA and electrophilic substitution with N-halosuccinimides proceeded with inversion to provide the corresponding allene in high yield and regioselectivity. Alternatively
The reaction of PdCl(2) with diethanolammonium chloride (DEAxHCl), in the molar ratio 1:2, affords the [HDEA](2)[PdCl(4)] complex (1). The hydrolytic activity of the novel Pd(II) complex 1 was tested in reaction with N-acetylated L-histidylglycine dipeptide (AcHis-Gly). Complex 1, as well
Two new tetranuclear complexes, [Zn(2)Cr(2)(NCS)(4)(Dea)(2)(HDea)(2)].4DMSO (1; DMSO = dimethyl sulfoxide) and [Zn(2)Cr(2)(NCS)(4)(Dea)(2)(HDea)(2)].2CH(3)CN (2), were prepared from zinc oxide, Reinecke's salt, NH(4)[Cr(NCS)(4)(NH(3))(2)].H(2)O, ammonium thiocyanate, and a nonaqueous solution of diethanolamine (H(2)Dea) in a reaction carried out under open air. Both compounds
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