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MilliporeSigma

148083

Sigma-Aldrich

1,1,1-Tris(hydroxymethyl)propane

97%

Sinónimos:

2-Ethyl-2-hydroxymethyl-1,3-propanediol, Trimethylolpropane

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About This Item

Fórmula lineal:
CH3CH2C(CH2OH)3
Número de CAS:
Peso molecular:
134.17
Beilstein/REAXYS Number:
1698309
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

4.8 (vs air)

Quality Level

vapor pressure

<1 mmHg ( 20 °C)

assay

97%

form

(Powder or Crystals or Granules or Chunks)

autoignition temp.

1301 °F

bp

159-161 °C/2 mmHg (lit.)

mp

56-58 °C (lit.)

SMILES string

CCC(CO)(CO)CO

InChI

1S/C6H14O3/c1-2-6(3-7,4-8)5-9/h7-9H,2-5H2,1H3

InChI key

ZJCCRDAZUWHFQH-UHFFFAOYSA-N

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Application

1,1,1-Tris(hydroxymethyl)propane was used as hydrogen bond-donating agent during triol-promoted activation of the C-F bond of benzylic fluorides. It was used in synthesis of new octanuclear manganese cluster and hyperbranched polyethers.

pictograms

Health hazard

signalword

Warning

hcodes

Hazard Classifications

Repr. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

356.0 °F - Cleveland open cup

flash_point_c

180 °C - Cleveland open cup

ppe

Eyeshields, Gloves, type N95 (US)


Certificados de análisis (COA)

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Hyperbranched aliphatic polyethers obtained from environmentally benign monomer: glycerol carbonate.
Rokicki G, et al.
Green Chemistry, 7(7), 529-539 (2005)
Pier Alexandre Champagne et al.
Beilstein journal of organic chemistry, 9, 2451-2456 (2013-12-25)
Activation of the C-F bond of benzylic fluorides was achieved using 1,1,1-tris(hydroxymethyl)propane (2) as a hydrogen bond-donating agent. Investigations demonstrated that hydrogen bond-donating solvents are promoting the activation and hydrogen bond-accepting ones are hindering it. However, the reaction is best
Stephanie E A Gratton et al.
Journal of controlled release : official journal of the Controlled Release Society, 121(1-2), 10-18 (2007-07-24)
A novel method for the fabrication of polymeric particles on the order of tens of nanometers to several microns is described. This imprint lithographic technique called PRINT (Particle Replication In Non-wetting Templates), takes advantage of the unique properties of elastomeric
Daniel Cohn et al.
Biomaterials, 25(27), 5875-5884 (2004-06-03)
This article introduces novel biocompatible tissue adhesives that do not involve any chemical or biochemical reactions, during their application in vivo. The use of these new adhesives is based exclusively on their temperature-dependent rheological properties. Since biocompatibility and biodegradability are
Constantinos J Milios et al.
Dalton transactions (Cambridge, England : 2003), (2)(2), 351-356 (2005-12-21)
The reaction between MnBr(2).4H(2)O with H(3)tmp (1,1,1-tris(hydroxymethyl)propane) in MeCN in the presence of Na(O(2)CCMe(3)) and NBu(4)Br produces the complex [Mn(8)(O(2)CCMe(3))(2)(tmp)(2)(Htmp)(4)Br(4)(H(2)O)(2)].2MeCN (1.2MeCN) in good yield. The centrosymmetric octanuclear molecule consists of four Mn(III) and four Mn(II) ions assembled together by fourteen

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