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  • Controlled synthesis of homopolymers and block copolymers based on 2-(acetoacetoxy)ethyl methacrylate via RAFT radical polymerisation.

Controlled synthesis of homopolymers and block copolymers based on 2-(acetoacetoxy)ethyl methacrylate via RAFT radical polymerisation.

Chemical communications (Cambridge, England) (2003-03-18)
Theodora Krasia, Rémi Soula, Hans G Börner, Helmut Schlaad
ABSTRACT

Reversible addition-fragmentation chain transfer (RAFT) radical polymerisation enables to synthesise well-defined homopolymers and block copolymers based on 2-(acetoacetoxy)ethyl methacrylate, which are capable to strongly coordinate to metals and metal ions.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
tert-Butyl α-bromoisobutyrate, ≥98.0%