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  • Selective sensing of Cu(II) at ng ml(-1) level based on phosphorescence quenching of 1-bromo-2-methylnaphthalene sandwiched in sodium deoxycholate dimer.

Selective sensing of Cu(II) at ng ml(-1) level based on phosphorescence quenching of 1-bromo-2-methylnaphthalene sandwiched in sodium deoxycholate dimer.

Chemical communications (Cambridge, England) (2005-02-19)
Yu Wang, Jian-Jun Wu, Yu-Feng Wang, Li-Pin Qin, Wei-Jun Jin
ABSTRACT

Using sodium deoxycholate as a protective medium, the selective recognition of Cu(II) at ng ml(-1) level is realized through dynamic phosphorescence quenching of 1-bromo-2-methylnaphthalene (BMN) without deoxygenation. The limit of detection is 4.32 ng ml(-1), and the relative standard deviation is 1% at 10 microM, linear up to 1 x 10(-5) M.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
2-Methylnaphthalene (β), 95%
Supelco
2-Methylnaphthalene, analytical standard