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Total synthesis of (+)-strictifolione.

Organic letters (2003-05-24)
Samir BouzBouz, Janine Cossy
ABSTRACT

[reaction: see text] The synthesis of (+)-strictifolione was achieved from 3-phenylproprionaldehyde by using enantioselective allyltitanations to control the stereogenic centers at C6, C4', and C6' and a cross-methathesis to control the configuration of the double bond at C1'-C2'.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Hydrocinnamaldehyde, technical grade, 90%