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222321

Sigma-Aldrich

Sodium carbonate

ACS reagent, anhydrous, ≥99.5%, powder or granules

Synonym(s):

Calcined soda, Carbonic acid disodium salt, Soda ash

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About This Item

Linear Formula:
Na2CO3
CAS Number:
Molecular Weight:
105.99
Beilstein/REAXYS Number:
4154566
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent
anhydrous

Quality Level

agency

suitable for SM 4500 - NH3

assay

≥99.5%

form

powder or granules

impurities

≤0.005% silica
≤0.01% insolubles

loss

≤1.0% loss on heating, 285 °C

pH

12 (25 °C, 106 g/L)

mp

851 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
phosphate (PO43-): ≤0.001%
sulfur compounds (as SO42-): ≤0.003%

cation traces

Ca: ≤0.03%
Fe: ≤5 ppm
K: ≤0.005%
Mg: ≤0.005%
heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

O=C(O[Na])O[Na]

InChI

1S/CH2O3.2Na/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

CDBYLPFSWZWCQE-UHFFFAOYSA-L

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General description

Sodium carbonate (Soda) is a white salt. It can be synthesized by the electrolysis of the molten sodium hydroxide or sodium chloride.
Sodium carbonate is a water soluble inorganic salt commonly used as a weak base. Its aqueous solution has the ability to uptake carbon dioxide. It can also catalyze the conversion of sewage sludge to liquid fuels.

Application

Sodium carbonate may be used as a reducing agent for the preparation of graphene sheets with good electrocapacity from graphene oxide dispersion.
It may also be used in procedures for the synthesis of the following:
  • Biaryls via palladium-catalyzed cross-coupling reaction of phenylboronicacid with haloarenes.
  • Chalcones and azachalcones via aldol condensation of aldehydes with ketones in aqueous medium.
  • Enynes via copper-catalyzed allylation of functionalized alkynes.
Sodium carbonate may be used in the following studies:
  • Determination of total polyphenolic index of wine products from grape by the Folin-Ciocalteu method.
  • To compose the ELISA (Enzyme-Linked Immunosorbent Assay) coating buffer.
  • Preparation of the antibody coating buffer for use in IGF-I kinase receptor activation assay (KIRA) assay.

Biochem/physiol Actions

Buffer component, may be used for the removal of peripheral membrane proteins.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Copper catalyzed regioselective coupling of allylic halides and alkynes promoted by weak inorganic bases.
Bieber LW and da Silva MF
Tetrahedron Letters, 48(40) , 7088-7090 (2007)
Liquid fuel production from sewage sludge by catalytic conversion using sodium carbonate.
Yokoyama S-Y, et al.
Fuel: The Science and Technology of Fuel and Energy, 66(8), 1150-1155 (1987)
A green and efficient method to produce graphene for electrochemical capacitors from graphene oxide using sodium carbonate as a reducing agent.
Jin Y, et al.
Applied Surface Science, 268, 541-546 (2013)
Efficient and clean aldol condensation catalyzed by sodium carbonate in water.
Zhang Z, et al.
Chemistry Letters (Jpn), 32(10), 966-967 (2003)
The palladium-catalyzed cross-coupling reaction of phenylboronic acid with haloarenes in the presence of bases.
Miyaura N, et al.
Synthetic Communications, 11(7), 513-519 (1981)

Articles

Development and validation of a fatty acid methyl esterification method, using methanolic HCl reagent, for FAME analysis by GC of vegetable oils and fats.

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