433810

(−)-Bis[(S)-1-phenylethyl]amine

99%

• Synonym(s): (−)-Bis[(S)-α-methylbenzyl]amine, [S-(R*,R*)]-(−)-Bis(α-methylbenzyl)amine
• Linear Formula: [C₆H₅CH(CH₃)]₂NH
• CAS Number: 56210-72-1
• Molecular Weight: 225.33
• MDL number: MFCD00243087
• UNSPSC Code: 12352116
• PubChem Substance ID: 24866982
• NACRES: NA.22

Properties

• assay: 99%
• form: liquid
• optical activity: [α]/D −159°, c = 2 in ethanol
• optical purity: ee: ≥99% (GLC)
• refractive index: n20/D 1.5525 (lit.)
• bp: 86 °C/0.05 mmHg (lit.)
• density: 0.987 g/mL at 25 °C (lit.)
• SMILES string: C[C@H](N[C@@H](C)c1ccccc1)c2ccccc2
• InChI: 1S/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/t13-,14-/m0/s1
• InChI key: NXLACVVNHYIYJN-KBPBESRZSA-N

Description

Application

(−)-Bis[(S)-1-phenylethyl]amine can be used as:

• A key intermediate in the synthesis of phosphoramidite (Feringa) ligands.
• A reactant in the preparation of C(18)-C(24) unit of a novel macrolide compound lasonolide A.
• A starting material in the synthesis of tacrine−huperzine A hybrid.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: >235.4 °F - closed cup
• flash_point_c: > 113 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter