16571

(+)-3-Bromocamphor

purum, ≥97.0% (sum of enantiomers, GC)

• Synonym(s): endo-(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
• Empirical Formula (Hill Notation): C₁₀H₁₅BrO
• CAS Number: 10293-06-8
• Molecular Weight: 231.13
• Beilstein/REAXYS Number: 3197237
• EC Number: 233-652-1
• MDL number: MFCD00003744
• UNSPSC Code: 12352115
• PubChem Substance ID: 57647579
• NACRES: NA.22

Properties

• grade: purum
• assay: ≥97.0% (sum of enantiomers, GC)
• form: solid
• optical activity: [α]20/D +136±3°, c = 1% in ethanol
• mp: 75-77 °C
• functional group: bromo; ketone
• SMILES string: [H][C@@]12CC[C@@](C)(C(=O)[C@H]1Br)C2(C)C
• InChI: 1S/C10H15BrO/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6-7H,4-5H2,1-3H3/t6-,7+,10+/m1/s1
• InChI key: NJQADTYRAYFBJN-FWWHASMVSA-N

Description

Application

• Insights into the mechanisms of within-species variation in sensitivity to chemicals: A case study using daphnids exposed to CMIT/MIT biocide.: This study investigates the differential sensitivity of daphnids to 2-Methyl-4-isothiazolin-3-one, highlighting the biochemical mechanisms underlying these variations. The findings provide crucial insights for environmental safety assessments (Kim et al., 2023).

Other Notes

Use as chiral building block; Debromo-silylation and -phosphonylation

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves