121908

Neocuproine hydrate

99%

• Synonym(s): 2,9-Dimethyl-1,10-phenanthroline hydrate
• Empirical Formula (Hill Notation): C₁₄H₁₂N₂ · xH₂O
• CAS Number: 654054-57-6
• Molecular Weight: 208.26 (anhydrous basis)
• NACRES: NA.22
• PubChem Substance ID: 24847471
• UNSPSC Code: 12352100
• EC Number: 207-601-9
• MDL number: MFCD00149306
• Assay: 99%

Properties

• Quality Segment: 100
• assay: 99%
• manufacturer/tradename: ECACC
• solubility: methanol: soluble 50 mg/mL, clear, colorless to dark yellow
• SMILES string: [H]O[H].Cc1ccc2ccc3ccc(C)nc3c2n1
• InChI: 1S/C14H12N2.H2O/c1-9-3-5-11-7-8-12-6-4-10(2)16-14(12)13(11)15-9;/h3-8H,1-2H3;1H2
• InChI key: MFZBSWSCIWCRKS-UHFFFAOYSA-N

Description

General description

Neocuproine hydrate is chelating agent and forms complex with Cu⁺ formed by reduction of Cu⁺² by hydroxylamine hydrochloride and produces electrochemiluminescence. It is an efficient ligand for alcohol oxidation with palladium in 1:1 water/DMSO mixtures.

Application

Neocuproine hydrate was used in determination of copper ions in aqueous solution using electrochemiluminescence.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• ppe: dust mask type N95 (US), Eyeshields, Gloves