Skip to Content
MilliporeSigma
All Photos(2)

Documents

328251

Sigma-Aldrich

Tetramethylammonium hydroxide solution

10 wt. % in H2O

Synonym(s):

N,N,N-trimethyl-methanaminium hydroxide, TMAH, TMAOH

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
(CH3)4N(OH)
CAS Number:
75-59-2
Molecular Weight:
91.15
Beilstein/REAXYS Number:
3558708
MDL number:
MFCD00008280
UNSPSC Code:
12352100
PubChem Substance ID:
24859725
NACRES:
NA.21

vapor pressure

17.5 mmHg ( 20 °C)

Quality Level

100

concentration

10 wt. % in H2O

refractive index

n20/D 1.3521

density

1.006 g/mL at 25 °C

SMILES string

[OH-].C[N+](C)(C)C

InChI

1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1

InChI key

WGTYBPLFGIVFAS-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

General description

Tetramethylammonium hydroxide (TMAH), is a commercially available quaternary ammonium base with significantly higher basicity than ammonium hydroxide.

Application

Tetramethylammonium hydroxide solution (10 wt. % in H2O) can be used as:      
  • A reactant to synthesize epoxy-polyhedral oligomeric silsesquioxanes (EPOSS) via sol-gel method using 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane (ECTMS) in IPA.     
  • An ionic liquid to modify SnO2 nanocrystals, which are applicable as an efficient electron transport layer in perovskite solar cells.

TMAH can also be used as an anisotropic etchant for silicon due to its high silicon etching rate. The main advantage of using TMAH is that it causes no danger to electrical circuits due to the absence of alkali ions.

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1 Dermal - STOT SE 1

target_organs

Central nervous system, Liver,thymus

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCCL4821
BCCJ5659
BCCG6900
STBJ6189
STBJ0919

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Vladislav V Lobodin et al.
Analytical chemistry, 85(16), 7803-7808 (2013-08-08)
Ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS) enables the direct characterization of complex mixtures without prior fractionation. High mass resolution can distinguish peaks separated by as little as 1.1 mDa), and high mass accuracy enables assignment of
Jong Tae Leem et al.
Polymers, 13(10) (2021-06-03)
EPOSS of polyhedral oligomeric silsesquioxanes (POSS) mixture structure and LPSQ of ladder-like polysilsesquioxane (LPSQ) structure were synthesized via sol-gel reaction. EPSQ had a high molecular weight due to polycondensation by potassium carbonate. The EPSQ film showed uniform surface morphology due
Lina Barreto et al.
Eukaryotic cell, 10(9), 1241-1250 (2011-07-05)
Potassium homeostasis is crucial for living cells. In the yeast Saccharomyces cerevisiae, the uptake of potassium is driven by the electrochemical gradient generated by the Pma1 H(+)-ATPase, and this process represents a major consumer of the gradient. We considered that
Qin Chen et al.
Bioresource technology, 117, 186-192 (2012-05-23)
The aim of this study was to explore the synergies of laccase, a ligninolytic enzyme, with cellulose and hemicellulase amendments on ensiled corn stover. Molecular signals of lignin decomposition were observed by tetramethylammonium hydroxide thermochemolysis and gas chromatography-mass spectroscopy (TMAH-GC-MS)
Hui Chong et al.
Langmuir : the ACS journal of surfaces and colloids, 28(4), 2091-2098 (2011-11-08)
A new water-soluble conjugated polymer containing fluorene and boron-dipyrromethene repeat units in the backbones (PBF) that exhibits red emission was synthesized and characterized. Cationic PBF forms uniform nanoparticles with negatively charged disodium salt 3,3'-dithiodipropionic acid (SDPA) in aqueous solution through
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service