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P33402

Sigma-Aldrich

2-Phenylpyridine

greener alternative

98%

Synonym(s):

α-Phenylpyridine, o-Phenylpyridine

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About This Item

Empirical Formula (Hill Notation):
C11H9N
CAS Number:
Molecular Weight:
155.20
Beilstein/REAXYS Number:
110445
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

98%

greener alternative product score

old score: 2
new score: 1
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greener alternative product characteristics

Atom Economy
Design for Energy Efficiency
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

refractive index

n20/D 1.623 (lit.)

bp

268-270 °C (lit.)

density

1.086 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

c1ccc(cc1)-c2ccccn2

InChI

1S/C11H9N/c1-2-6-10(7-3-1)11-8-4-5-9-12-11/h1-9H

InChI key

VQGHOUODWALEFC-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Atom Economy”, “Design for Energy Efficiency” and “Use of Renewable Feedstock”. Click here to view its DOZN scorecard.

application

Versatile synthetic intermediate.

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pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

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Huazhou Wu et al.
Dalton transactions (Cambridge, England : 2003), 40(9), 1969-1976 (2011-02-02)
Iridium(III) complexes with intense phosphorescence in solution have been widely applied in organic light-emitting diodes, chemosensors and bioimaging. However, little attention has been paid to iridium(III) complexes showing weak phosphorescence in solution and enhanced phosphorescence emission in the solid state
Palladium-catalyzed methylation of aryl C-H bond by using peroxides.
Yuhua Zhang et al.
Journal of the American Chemical Society, 130(10), 2900-2901 (2008-02-14)
Michael T Vagnini et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(39), 15651-15656 (2012-05-16)
Photodriving the activity of water-oxidation catalysts is a critical step toward generating fuel from sunlight. The design of a system with optimal energetics and kinetics requires a mechanistic understanding of the single-electron transfer events in catalyst activation. To this end
Dik-Lung Ma et al.
Journal of the American Chemical Society, 131(5), 1835-1846 (2008-11-13)
A series of platinum(II) complexes containing dipyridophenazine (dppz) and C-deprotonated 2-phenylpyridine (N-CH) ligands were prepared and assayed for G-quadruplex DNA binding activities. [PtII(dppz-COOH)(N-C)]CF3SO3 (1; dppz-COOH = 11-carboxydipyrido[3,2-a:2',3'-c]phenazine) binds G-quadruplex DNA through an external end-stacking mode with a binding affinity of
Linda S Jongbloed et al.
European journal of inorganic chemistry, 2018(20-21), 2408-2418 (2018-06-26)
Based on previous work related to the design and application of rigid tridentate phosphine-pyridine-phenyl coordination offered by a PNC-pincer ligand upon cyclometalation to nickel, the synthesis, spectroscopic and solid state characterization and redox-reactivity of two NiII(PNC) complexes featuring either a

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