ALD00458

Sodium 2-(3-Bromophenyl)-1,1-difluoroethanesulfinate

• Empirical Formula (Hill Notation): C₈H₆BrF₂NaO₂S
• CAS Number: 1934559-24-6
• Molecular Weight: 307.09
• UNSPSC Code: 12352101
• PubChem Substance ID: 329772686
• NACRES: NA.22

Properties

• form: powder
• Quality Level: 100
• reaction suitability: reaction type: C-C Bond Formation; reagent type: catalyst; reaction type: C-H Activation
• mp: 250 °C
• SMILES string: BrC1=CC(CC(F)(F)S(O[Na])=O)=CC=C1
• InChI: 1S/C8H7BrF2O2S.Na/c9-7-3-1-2-6(4-7)5-8(10,11)14(12)13;/h1-4H,5H2,(H,12,13);/q;+1/p-1
• InChI key: YFTINOJKNRSGLP-UHFFFAOYSA-M

Description

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Other Notes

Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope; Tunability; and Predictability

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable