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934003

Sigma-Aldrich

Methyl (2,2,2-trifluoroethyl) carbonate

greener alternative

≥98%, anhydrous, battery grade

Synonym(s):

Carbonic Acid Methyl 2,2,2-Trifluoroethyl Ester, FEMC

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About This Item

Empirical Formula (Hill Notation):
C4H5F3O3
CAS Number:
Molecular Weight:
158.08
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

grade

battery grade

Quality Level

assay

≥98%

form

liquid

greener alternative product characteristics

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impurities

≤250 ppm HF
≤300 ppm H2O

bp

57-59 °C/120 mmHg
90 °C (lit.)

density

1.34 g/mL (lit.)

application(s)

battery manufacturing

greener alternative category

General description

Methyl (2,2,2-trifluoroethyl) carbonate (FEMC), ≥99%, battery grade is one kind of fluorinated linear carbonate. It comes with very low water content (≤ 300.0 ppm) and low impurity of HF (≤ 250.0 ppm) which is ideal for battery research
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Application

Battery-grade methyl (2,2,2-trifluoroethyl) carbonate (FEMC) is an effective additive for improving the performance and stability of lithium-ion batteries. Its outstanding thermal and electrochemical stability makes it a reliable option for high-temperature and high-voltage battery applications. FEMC has been shown to improve battery life, enhance energy density, and increase cycling stability. As an electrolyte additive in lithium-ion batteries (LIBs), FEMC plays an important role in forming a stable solid electrolyte interphase (SEI) and effective passivation of the cathode surfaces, resulting in enhanced discharge capacity and cyclability. Even the addition of 5 wt % of FEMC was found to be very effective in forming a stable SEI layer and protecting the surface of the cathode. FEMC′s high performance makes it an attractive choice for battery manufacturers looking to create safe and efficient battery products.

pictograms

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Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

100.4 °F

flash_point_c

38 °C


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Fluorinated Carbonate-Based Electrolyte for High-Voltage Li(Ni0.5Mn0.3Co0.2)O2/Graphite Lithium-Ion Battery
Jinsol Im, et al.
Journal of the Electrochemical Society, 164 (2017)
Building Safe Lithium-Ion Batteries for Electric Vehicles: A Review
Duan J, et al.
Electrochemical Energy Reviews, 3, 1-42 (2020)
Interfacial Origin of Performance Improvement and Fade for 4.6 V. LiNi0.5Co0.2Mn0.3O2 Battery Cathodes
Lee Yu-Mi, et al.
The Journal of Physical Chemistry C, 118, 10631?10639-10631?10639 (2014)

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