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926132

Sigma-Aldrich

(R,R)-Ms-DENEB™

Synonym(s):

stereoisomer of Chloro[N-[(1R,2R)-2-[(S)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]methanesulfonamidato-κN]ruthenium

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About This Item

Empirical Formula (Hill Notation):
C25H29ClN2O3RuS
CAS Number:
1333981-86-4
Molecular Weight:
574.10
UNSPSC Code:
12161600
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

reagent type: ligand

functional group

phosphine

Application

(R,R)-Ms-DENEB™ is an oxo-tethered ruthenium complex for use as an efficient asymmetric hydrogenation catalyst.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Packaging

Package under a dry inert gas.

Other Notes

Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H2 Hydrogenation

Legal Information

Product of Takasago. For research and development purposes only. PCT/JP2011/064490
DENEB is a trademark of Takasago Intl. Corp.

related product

Product No.
Description
Pricing

926116

(R,R)-Ts-DENEB™

926140

(S,S)-Ms-DENEB™

926124

(S,S)-Ts-DENEB™

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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Taichiro Touge et al.
Journal of the American Chemical Society, 133(38), 14960-14963 (2011-08-30)
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high

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