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688614

Sigma-Aldrich

Basolite® C 300

greener alternative

produced by BASF

Synonym(s):

Copper benzene-1,3,5-tricarboxylate, Cu-BTC MOF, HKUST-1

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About This Item

Empirical Formula (Hill Notation):
C18H6Cu3O12
Molecular Weight:
604.87
MDL number:
MFCD10567003
UNSPSC Code:
26111700
PubChem Substance ID:
329761179
NACRES:
NA.23

grade

produced by BASF

form

solid

reaction suitability

reagent type: catalyst
core: copper

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

surface area

1500-2100 m2/g

particle size distribution

15.96 μm (D50)

bulk density

0.35 g/cm3

greener alternative category

, Enabling

SMILES string

O=C(O[Cu]OC(=O)c1cc2cc(c1)C(=O)O[Cu]OC2=O)c3cc4cc(c3)C(=O)O[Cu]OC4=O

InChI

1S/2C9H6O6.3Cu/c2*10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15;;;/h2*1-3H,(H,10,11)(H,12,13)(H,14,15);;;/q;;3*+2/p-6

InChI key

NOSIKKRVQUQXEJ-UHFFFAOYSA-H

General description

Basolite®C 300 is a metal organic framework (MOF). It is a crystallized hybrid porous solid built up from inorganic subunits, which are connected to organic linkers such as carboxylates or phosphonates. It is a commercialized sorbent that has the structure of HKUST-1.
HKUST-1 is also known as MOF-199, Cu-BTC and Basolite(TM) C300. HKUST-1 is a blue cubic crystal of copper based ultramicroporous metal framework (MOF). It is prepared by solvothermal method. It could have a surface area of nearly 2200 m2/g2.
MOF (metal organic framework)
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Basolite®C 300 can be used in the adsorption of carbon dioxide, carbon monoxide, and liquid absorption of dibenzothiopene.
Used for gas adsorption (carbon dioxide, nitrogen, oxygen, hydrogen gas), catalysis, and separations

Other Notes

can be reactivated at 200°C (vacuum)

Legal Information

Basolite is a registered trademark of BASF SE

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chuanhui Huang et al.
Nature communications, 10(1), 2779-2779 (2019-06-27)
Optimising the supported modes of atom or ion dispersal onto substrates, to synchronously integrate high reactivity and robust stability in catalytic conversion, is an important yet challenging area of research. Here, theoretical calculations first show that three-coordinated copper (Cu) sites
Dan Ping Wang et al.
Journal of colloid and interface science, 529, 265-272 (2018-06-17)
A mesoporous octahedral copper oxide@titania (CuO/TiO2) composites with core-shelled structure have been successfully fabricated via a facile and cost-effective approach, which involves two main steps: the creation of homogeneous TiO2 shell onto the octahedral Cu-based metal-organic frameworks (MOFs) template and
Fabrication of metal-organic framework-containing silica-colloidal crystals for vapor sensing.
Guang Lu et al.
Advanced materials (Deerfield Beach, Fla.), 23(38), 4449-4452 (2011-08-23)
Nak Cheon Jeong et al.
Journal of the American Chemical Society, 134(1), 51-54 (2011-12-14)
HKUST-1, a metal-organic framework (MOF) material containing Cu(II)-paddlewheel-type nodes and 1,3,5-benzenetricarboxylate struts, features accessible Cu(II) sites to which solvent or other desired molecules can be intentionally coordinated. As part of a broader investigation of ionic conductivity in MOFs, we unexpectedly
Heba Ahmed et al.
Nature communications, 10(1), 2282-2282 (2019-05-28)
The high surface area and porosity, and limitless compound and network combinations between the metal ions and organic ligands making up metal-organic frameworks (MOFs) offer tremendous opportunities for their use in many applications. While numerous methods have been proposed for
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