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687952

Sigma-Aldrich

(Cyclohexylmethyl)magnesium bromide solution

Synonym(s):

Cyclohexylmethylmagnesium bromide

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50 ML
$145.50

$145.50

List Price$291.00Save 50%
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Available to ship onDecember 11, 2024Details

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50 ML
$145.50

About This Item

Empirical Formula (Hill Notation):
C7H13BrMg
CAS Number:
35166-78-0
Molecular Weight:
201.39
MDL number:
MFCD02260210
UNSPSC Code:
12352103
PubChem Substance ID:
329760828
NACRES:
NA.22

$145.50

List Price$291.00Save 50%
Availability

Available to ship onDecember 11, 2024Details

Request a Bulk Order

form

liquid

reaction suitability

reaction type: Grignard Reaction

density

0.966 g/mL at 25 °C

SMILES string

Br[Mg]CC1CCCCC1

InChI

1S/C7H13.BrH.Mg/c1-7-5-3-2-4-6-7;;/h7H,1-6H2;1H;/q;;+1/p-1

InChI key

ZBCIOGFGZRNNEC-UHFFFAOYSA-M

Application

Reactant involved in:
  • Isomerization polymerization of alkenylcyclohexanes
  • Intramolecular rearrangements of vinylidenecyclopropanes
  • Cycloisomerization of cyclic and acyclic enynes

Additionally reactant involved in synthesis of biologically active molecules including:
  • Dipeptidyl boronic acid proteasome inhibitors
  • Substituted 1,3-dihydroindole-2-ones with antitumor effects
  • Sulfur-free transition state nucleoside analog inhibitors of methylthioadenosine nucleosidase and phosphorylase

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH014,EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-4.0 °F

flash_point_c

-20 °C

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Questions

  1. What solution is this in (ie: THF)? What is the concentration (ie: 0.2M, 1M, 2M...)?

    1 answer

    1. The concentration of this product ranges from 0.40 - 0.60 M in THF. The exact concentration is listed on the lot-specific Certificate of Analysis. Please see the sample Certificate of Analysis: https://www.sigmaaldrich.com/certificates/sapfs/PROD/sap/certificate_pdfs/COFA/Q14/687952-50ML0000235108.pdf

      Please see the link below to the SDS which lists each component in Section 3:
      https://www.sigmaaldrich.com/sds/aldrich/687952

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