671800

Di(1-adamantyl)benzylphosphine

95%

• Synonym(s): cataCXium^® ABn
• Empirical Formula (Hill Notation): C₂₇H₃₇P
• CAS Number: 395116-70-8
• Molecular Weight: 392.56
• Beilstein/REAXYS Number: 9359745
• MDL number: MFCD05861603
• UNSPSC Code: 12352002
• PubChem Substance ID: 329760443
• NACRES: NA.22

Properties

• assay: 95%
• form: solid
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Asymmetric synthesis
• functional group: phosphine
• SMILES string: C1[C@H]2C[C@H]3C[C@@H]1C[C@@](C2)(C3)P(Cc4ccccc4)[C@@]56C[C@@H]7C[C@@H](C[C@@H](C7)C5)C6
• InChI: 1S/C27H37P/c1-2-4-19(5-3-1)18-28(26-12-20-6-21(13-26)8-22(7-20)14-26)27-15-23-9-24(16-27)11-25(10-23)17-27/h1-5,20-25H,6-18H2/t20-,21+,22-,23-,24+,25-,26-,27-
• InChI key: ANIAFEJRWQDKDV-ANIFQACUSA-N

Description

General description

sold in collaboration with Solvias AG

application

Catalyst for:

• Sonogashira coupling reaction
• Ruthenium-catalyzed amination of secondary alcohols. with ammonia
• Rhodium-catalyzed regioselective hydroformylation of alkenes
• Reductive carbonylation
• Suzuki coupling reaction

Legal Information

US7148176

cataCXium is a registered trademark of Umicore AG & Co. KG

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)