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Sigma-Aldrich

Diethyl allyl phosphate

98%

Synonym(s):

Allyl ethyl phosphate, Diethyl 2-propen-1-yl phosphate

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About This Item

Linear Formula:
H2C=CHCH2OP(O)(OC2H5)2
CAS Number:
3066-75-9
Molecular Weight:
194.17
MDL number:
MFCD02683550
UNSPSC Code:
12352100
PubChem Substance ID:
24874513
NACRES:
NA.22

assay

98%

refractive index

n20/D 1.422 (lit.)

bp

45-46 °C (lit.)

density

1.09 g/mL at 25 °C (lit.)

SMILES string

CCOP(=O)(OCC)OCC=C

InChI

1S/C7H15O4P/c1-4-7-11-12(8,9-5-2)10-6-3/h4H,1,5-7H2,2-3H3

InChI key

GZNJJEODYYLYSA-UHFFFAOYSA-N

General description

Diethyl allyl phosphate can be prepared by reacting ethanol and POCl3.It can undergo free radical polymerization to form a flame retardant polymer, poly DEAP

Application

DEAP may be used as a flame retardant additive in the preparation of rubber wood/polymer composite. It can also be used for the stereoselective synthesis of cis- or trans-3-vinyl-β-lactam compounds and also for the fabrication of amphoteric surfaces on silicone substrates.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A new polymeric flame retardant additive for vinyl polymers.
Sundarrajan S, et al.
Indian J. Chem. A, 40(1), 41-45 (2001)
Carbonylative [2+ 2] cycloaddition for the construction of ?-lactam skeleton with palladium catalyst.
Torii S, et al.
Tetrahedron Letters, 34(41), 6553-6556 (1993)
Ebru Akdoğan et al.
Colloids and surfaces. B, Biointerfaces, 89, 289-294 (2011-10-04)
Amphoteric surfaces were generated on silicone substrates via plasma polymerization technique using a single monomer; diethyl allyl phosphate (DAP). Surface characterization was performed by the means of contact angle titration and Fourier transform infrared (FTIR) spectroscopy. The surface of silicone
Modification of rubber wood with styrene in combination with diethyl allyl phosphate as the flame-retardant agent.
Devi RR, et al.
Journal of Applied Polymer Science, 105(5), 2461-2467 (2007)

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