522902

(S)-(+)-2-Methylpiperidine

97%

• Empirical Formula (Hill Notation): C₆H₁₃N
• CAS Number: 3197-42-0
• Molecular Weight: 99.17
• MDL number: MFCD01862169
• UNSPSC Code: 12352005
• PubChem Substance ID: 24874282
• NACRES: NA.22

Properties

• assay: 97%
• optical activity: [α]20/D +35°, c = 3.5 in hexane
• refractive index: n20/D 1.446 (lit.)
• bp: 117-121 °C (lit.)
• density: 0.823 g/mL at 25 °C (lit.)
• SMILES string: C[C@H]1CCCCN1
• InChI: 1S/C6H13N/c1-6-4-2-3-5-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1
• InChI key: NNWUEBIEOFQMSS-LURJTMIESA-N

Description

Application

(S)-(+)-2-Methylpiperidine has been used in the preparation of (S)-N-(3-(2-pipecolin-1-yl)propyl)phthalimide by reacting with N-(3-bromopropyl)phthalimide. It may also be used as a starting material in the multi-step synthesis of (2S,6S)-(+)-solenopsin A.

Safety Information

• pictograms: GHS02,GHS07
• signalword: Danger
• hcodes: H225,H315,H319,H335
• pcodes: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 60.0 °F - closed cup
• flash_point_c: 15.56 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter