Skip to Content
MilliporeSigma
All Photos(2)

Documents

430218

Sigma-Aldrich

Poly[4,4′-methylenebis(phenyl isocyanate)-alt-1,4-butanediol/di(propylene glycol)/polycaprolactone]

pellets, MDI-polyester/polyether polyurethane.

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

CAS Number:
68084-39-9
MDL number:
MFCD00217691
UNSPSC Code:
12162002
NACRES:
NA.23

abrasion resistance

10 mg (Taber, H-22 wheel)

form

beads
pellets

melt index

4 g/10 min (190°C/8.7kg)

hardness

84 (Shore A, ASTM D 2240)

transition temp

Tg −40 °C (DSC)
softening point 85 °C (Vicat, ASTM D 1525)

density

1.18 g/mL at 25 °C (lit.)

General description

Poly[4,4′-methylenebis(phenyl isocyanate)-alt-1,4-butanediol/di(propylene glycol)/polycaprolactone] (PU/PCL) is a polyurethane solution that can be used as a shape memory polymer and a reinforcing unit for enhancing the mechanical and thermal properties of the base materials. It is biocompatible and finds usage in endothelial proliferations. PU/PCL contains polycaprolactone (PCL) that facilitates the hydrophobic properties of the polymeric matrix.

Application

Automotive fascia, cable jackets, side trim, fabric laminates, health care tubing, catheters, transdermal patches and in seals casters, shoes, bushings and wheels.
PU/PCL can be used in the formation of a polyurethane membrane for effective gas separation. It can also be used to synthesize reinforced hydrogel with good thermo-mechanical properties for biomedical applications.

Features and Benefits

Tough, high-performance, wear-resistant elastomer with good clarity, chemical resistance, flexibility and toughness. Can be used in current form or further polymerized. Low compression set

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Strong fiber reinforced hydrogels for biomedical applications
2011 IEEE 37th Annual Northeast Bioengineering Conference (NEBEC), 9(2), 1-2 (2011)
3D Networked Graphene-Ferromagnetic Hybrids for Fast Shape Memory Polymers with Enhanced Mechanical Stiffness and Thermal Conductivity
Lee S, et al.
Small, 10(19), 3880-3886 (2014)
Gas separation in mixed matrix membranes based on polyurethane containing SiO2, ZSM-5, and ZIF-8 nanoparticles
Amedi HR and Aghajani M
Journal of Natural Gas Science and Engineering, 35(19), 695-702 (2016)
Zuo-jun Hu et al.
BMC cardiovascular disorders, 12, 115-115 (2012-12-05)
In a previous in vitro study, we confirmed that small-caliber nanofibrous polyurethane (PU) vascular grafts have favorable mechanical properties and biocompatibility. In the present study, we examined the in vivo biocompatibility and stability of these grafts. Forty-eight adult male beagle
The in vivo performance of small-caliber nanofibrous polyurethane vascular grafts
Hu Z, et al.
BMC Cardiovascular Disorders, 12(1), 115-115 (2012)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service