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334626

Sigma-Aldrich

Tin(II) fluoride

99%

Synonym(s):

Difluorostannylene, Stannous fluoride, Tin bifluoride, Tin difluoride

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100 G
$128.00

$128.00


Estimated to ship onApril 18, 2025


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100 G
$128.00

About This Item

Empirical Formula (Hill Notation):
F2Sn
CAS Number:
Molecular Weight:
156.71
EC Number:
MDL number:
UNSPSC Code:
12352202
PubChem Substance ID:
NACRES:
NA.22

$128.00


Estimated to ship onApril 18, 2025


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Quality Level

assay

99%

reaction suitability

core: tin
reagent type: catalyst

density

4.57 g/mL at 25 °C (lit.)

SMILES string

F[SnH2]F

InChI

1S/2FH.Sn/h2*1H;/q;;+2/p-2

InChI key

ANOBYBYXJXCGBS-UHFFFAOYSA-L

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Application

Tin(II) fluoride (SnF2) can be used:
  • As an inhibitor of Sn4+ in fabrication of formamidinium tin iodide (FASnI3) perovskite solar cells (PSCs) via SnF2–pyrazine complex formation.[1]
  • As a catalyst in glycerol ketalization,[2] Knoevenagel condensation and aldol-type reactions.[3]
  • In the synthesis of α, β-epoxy ketone from α, α-dibromoacetophenone and aliphatic and aromatic aldehyde via oxidative addition of carbon-halogen bonds.[3]
  • In the stereocontrolled [3 + 3] , [3 + 4], [3 + 5] annulations reactions.

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Molander, G. A.; Shubert, D. C.
Journal of the American Chemical Society, 109, 576-576 (1987)
Shoda, S.; Mukaiyama, T.
Chemistry Letters (Jpn), 723-723 (1981)
SnF2-catalyzed glycerol ketalization: A friendly environmentally process to synthesize solketal at room temperature over on solid and reusable Lewis acid
da Silva MJ, et al.
Chemical Engineering Journal, 307(12), 828-835 (2017)
Xiaoyang Pan et al.
Inorganic chemistry, 57(11), 6641-6647 (2018-05-19)
Noble metal nanoparticles have attracted considerable attention due to their useful capabilities as heterogeneous catalysts. However, they are usually prepared using various organic stabilizing agents that negatively affect their catalytic activities. Herein, we report a facile, clean, and effective method
Mingyu Hu et al.
Nature communications, 11(1), 151-151 (2020-01-11)
State-of-the-art halide perovskite solar cells have bandgaps larger than 1.45 eV, which restricts their potential for realizing the Shockley-Queisser limit. Previous search for low-bandgap (1.2 to 1.4 eV) halide perovskites has resulted in several candidates, but all are hybrid organic-inorganic compositions, raising potential concern regarding

Articles

Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.

Questions

  1. HI THIS QUESTION IS ABOUT PRODUCT # 34626 - TIN(ll) fluoride -99% SnF2 I WOULD LIKE TO KNOW THE DILUTION TO WATER INFORMATION ?

    1 answer
    1. This product is not tested for solubility, however it is reportedly soluble in water at 30 - 39 g/100mL.
      See the link to PubChem below for further solubility information:
      https://pubchem.ncbi.nlm.nih.gov/compound/24550#section=Solubility

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