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308315

Sigma-Aldrich

Lithium hexafluoroarsenate(V)

greener alternative

98%

Synonym(s):

Hexafluoroarsenate(V) lithium

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About This Item

Linear Formula:
LiAsF6
CAS Number:
Molecular Weight:
195.85
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

98%

form

powder

reaction suitability

reagent type: catalyst
core: arsenic

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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application(s)

battery manufacturing

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SMILES string

[Li+].F[As-](F)(F)(F)(F)F

InChI

1S/AsF6.Li/c2-1(3,4,5,6)7;/q-1;+1

InChI key

GTZQZEYBOGZTEO-UHFFFAOYSA-N

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General description

Lithium hexafluoroarsenate(V) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

The surface chemistry of Li electrodes in ethereal LiAsF6 was tested with new salts for potential battery systems.

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Ling-Yun Yang et al.
Angewandte Chemie (International ed. in English), 53(14), 3631-3635 (2014-03-07)
A new category of crystalline polymer electrolyte prepared by the supramolecular self-assembly of polyethylene oxide (PEO), α-cyclodextrin (α-CD), and LiAsF6 is reported. The polymer electrolyte consists of the nanochannels formed by α-CDs in which the PEO/Li(+) complexes are confined. The
Electrodes with high power and high capacity for rechargeable lithium batteries
Kang K, et al.
Science, 311(5763), 977-980 (2006)
Challenges for rechargeable Li batteries
Goodenough JB and Kim Y
Chemistry of Materials, 22(3), 587-603 (2009)
Towards greener and more sustainable batteries for electrical energy storage
Larcher D and Tarascon J
Nature Chemistry, 7(1), 19-19 (2015)
The Li-ion rechargeable battery: a perspective
Goodenough JB and Park K
Journal of the American Chemical Society, 135(4), 1167-1176 (2013)

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