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283711

Sigma-Aldrich

N,N,2,4,6-Pentamethylaniline

98%

Synonym(s):

N,N-Dimethylmesidine

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About This Item

Linear Formula:
(CH3)3C6H2N(CH3)2
CAS Number:
13021-15-3
Molecular Weight:
163.26
MDL number:
MFCD00010596
UNSPSC Code:
12352100
PubChem Substance ID:
24857127
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.512 (lit.)

bp

213-215 °C (lit.)

density

0.907 g/mL at 25 °C (lit.)

SMILES string

CN(C)c1c(C)cc(C)cc1C

InChI

1S/C11H17N/c1-8-6-9(2)11(12(4)5)10(3)7-8/h6-7H,1-5H3

InChI key

JZBZLRKFJWQZHU-UHFFFAOYSA-N

General description

N,N,2,4,6-Pentamethylaniline participates in condensation of dimeric 3,4,6-tri-O-acetyl-2-deoxy-2-nitroso-α-D-glucopyranosyl chloride with benzyl alcohol to yield an oximino glycoside.

Application

N,N,2,4,6-Pentamethylaniline was used in the synthesis of an oximino glycoside that was reduced with lithium aluminum hydride to benzyl 2-amino-2-deoxy-α-D-gluco- and -mannopyranoside hydrochloride.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

174.2 °F - closed cup

flash_point_c

79 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

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Synthesis of a β-D-linked disaccharide from dimeric tri-O-acetyl-2-deoxy-2-nitroso-α-D-glucopyranosyl chloride.
Miyai K and Jeanloz RW.
Carbohydrate Research, 21(1), 45-55 (1972)

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