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281069

Sigma-Aldrich

Azetidine

98%

Synonym(s):

Trimethylene imine

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250 MG
$61.60
1 G
$235.00

$61.60

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250 MG
$61.60
1 G
$235.00

About This Item

Empirical Formula (Hill Notation):
C3H7N
CAS Number:
503-29-7
Molecular Weight:
57.09
Beilstein/REAXYS Number:
102384
EC Number:
207-963-8
MDL number:
MFCD00005165
UNSPSC Code:
12352100
PubChem Substance ID:
24856966
NACRES:
NA.22
form:
liquid
assay:
98%

$61.60

In StockDetails

Request a Bulk Order

Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.432 (lit.)

bp

61-62 °C (lit.)

density

0.847 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C1CNC1

InChI

1S/C3H7N/c1-2-4-3-1/h4H,1-3H2

InChI key

HONIICLYMWZJFZ-UHFFFAOYSA-N

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General description

Phototransformations of azetidine radical cations in freonic matrices under the action of light with λ = 436nm has been investigated[1]. The IR spectrum of azetidine in solid argon matrices has been measured[2].

Application

Azetidine was employed in:
  • a high yielding palladium-catalyzed cross-coupling raection with aryl bromides[3]
  • Ullmann type coupling reaction with iodonitroflourenes[4]

accessory

Product No.
Description
Pricing

Pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

hcodes

H225,H314

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-4.0 °F

flash_point_c

-20 °C

ppe

Faceshields, Gloves, Goggles

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Certificates of Analysis (COA)

Lot/Batch Number
STBK8744
STBK4235
STBJ1922
STBH6592
STBG0071V

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Sigma-Aldrich

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Synthesis, 3245-3245 (2006)
Phototransformations of azetidine radical cations stabilized in freonic matrices.
Sorokin ID, et al.
High Energy Chemistry, 48(3), 180-184 (2014)
Experimental and computational studies of the structure and vibrational spectra of azetidine derivatives.
Thompson CA, et al.
Journal of Molecular Structure, 491(1), 67-80 (1999)
Synthesis, 243-243 (2007)
Milan Bera et al.
The Journal of organic chemistry, 74(22), 8814-8817 (2009-10-17)
[Ag(COD)(2)]PF(6) catalyzes the reaction between propargyl alcohols and N-tosylaziridines/azetidines leading to a diverse range of N,O-heterocycles, namely, oxazines, oxazepines, and oxazocines via ring-opening and ring-closing in a cascade.
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