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259039

Sigma-Aldrich

Chloro(1,5-hexadiene)rhodium(I),dimer

98%

Synonym(s):

Di-μ-chlorobis[(1,2,5,6-η)-1,5-hexadiene]dirhodium

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About This Item

Linear Formula:
[(H2C=CHCH2CH2CH=CH2)RhCl]2
CAS Number:
32965-49-4
Molecular Weight:
434.96
MDL number:
MFCD00064595
UNSPSC Code:
12161600
PubChem Substance ID:
24855679
NACRES:
NA.22

assay

98%

reaction suitability

core: rhodium
reagent type: catalyst

mp

118-120 °C (lit.)

SMILES string

Cl[Rh].Cl[Rh].C=CCCC=C.C=CCCC=C

InChI

1S/2C6H10.2ClH.2Rh/c2*1-3-5-6-4-2;;;;/h2*3-4H,1-2,5-6H2;2*1H;;/q;;;;2*+1/p-2

InChI key

HXNWPVBAYNUADR-UHFFFAOYSA-L

Application

Catalyst for:
  • Hydrogenation
  • Enantioselective hydrosilylation
Useful catalyst for the reduction of arenes and heterocyclic compounds using CTAB or THS as phase-transfer catalyst.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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Aldrichimica Acta, 18, 111-111 (1985)
Organometallics, 2, 1055-1055 (1983)

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