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181463

Sigma-Aldrich

Polyisobutylene

average Mw ~1,000,000, average Mn ~600,000 by GPC/MALLS, average Mv ~1,200,000

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About This Item

Linear Formula:
[CH2C(CH3)2]n
CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

solid (or Chunk(s))

mol wt

average Mn ~600,000 by GPC/MALLS
average Mv ~1,200,000
average Mw ~1,000,000

contains

500 ppm BHT as stabilizer

color

colorless, or white

refractive index

n20/D 1.51

density

0.92 g/mL at 25 °C (lit.)

SMILES string

CC(C)=C

InChI

1S/C4H8/c1-4(2)3/h1H2,2-3H3

InChI key

VQTUBCCKSQIDNK-UHFFFAOYSA-N

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Application

  • The use of polyisobutylene-based polymers in ophthalmology: Discusses the application of polyisobutylene-based polymers in ophthalmologic devices, highlighting its potential in biomedical applications (L Pinchuk, 2022).
  • Synthesis of a polyisobutylene-tagged fac-Ir (ppy) 3 complex and its application as recyclable visible-light photocatalyst in a continuous flow process: Presents a novel use of polyisobutylene as a support for photocatalysts, enhancing recyclability and efficiency in light-driven chemical reactions (D Rackl, P Kreitmeier, O Reiser, 2016).
  • Polyisobutylene-based thermoplastic elastomers for manufacturing polymeric heart valve leaflets: In vitro and in vivo results: Explores the use of polyisobutylene-based elastomers in the production of heart valve leaflets, assessing their physical properties and compatibility (E Ovcharenko et al., 2019).
  • Polyisobutylene—new opportunities for medical applications: Reviews the potential of polyisobutylene in various medical applications, focusing on its properties and benefits for healthcare materials (D Barczikai et al., 2021).
  • Homogeneous and heterogeneous catalysts for the synthesis of highly reactive polyisobutylene: discovery, development and perspectives: Discusses advancements in catalyst technology for producing high-reactivity polyisobutylene, crucial for high-performance materials (IV Vasilenko, SV Kostjuk, 2021).

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves


Certificates of Analysis (COA)

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David Cozzens et al.
Langmuir : the ACS journal of surfaces and colloids, 27(23), 14160-14168 (2011-10-26)
The surface properties and biocompatibility of a class of thermoplastic polyurethanes (TPUs) with applications in blood-contacting medical devices have been studied. Thin films of commercial TPUs and novel polyisobutylene (PIB)-poly(tetramethylene oxide) (PTMO) TPUs were characterized by contact angle measurements, X-ray
David Cozzens et al.
Journal of biomedical materials research. Part A, 95(3), 774-782 (2010-08-21)
Long term in vitro biostability of thermoplastic polyurethanes (TPUs) containing mixed polyisobutylene (PIB)/poly(tetramethylene oxide) (PTMO) soft segment was studied under accelerated conditions in 20% H(2)O(2) solution containing 0.1M CoCl(2) at 50 °C to predict resistance to metal ion oxidative degradation
Goy Teck Lim et al.
Biomacromolecules, 12(5), 1795-1799 (2011-04-01)
This paper is the first report of electrospinning neat polyisobutylene-based thermoplastic elastomers. Two generations of these materials are investigated: a linear poly(styrene-b-isobutylene-b-styrene) (L_SIBS) triblock copolymer and a dendritic poly(isobutylene-b-p-methylstyrene) (D_IB-MS), also a candidate for biomedical applications. Cross-polarized optical microscopy shows
Annalisa Calò et al.
Langmuir : the ACS journal of surfaces and colloids, 26(8), 5312-5315 (2010-03-26)
This work reports the application of a patterned thin film of polyisobutylene (PIB) irradiated with an electron beam as a time-temperature integrator, i.e., a device that is able to record the thermal history of a product. The device is fabricated
Deniz C Tuncaboylu et al.
Langmuir : the ACS journal of surfaces and colloids, 26(10), 7574-7581 (2010-01-29)
Organic-inorganic hybrid materials attract particular interest because of their excellent mechanical properties. Here, we report the synthesis of hybrid cryogels consisting of interpenetrated polyisobutylene and silica networks. The gels were prepared by cross-linking of butyl rubber in cyclohexane containing silica

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