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544981

Sigma-Aldrich

Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate

99.95% trace metals basis

Synonym(s):

Ru(BPY)3, Ruthenium-tris(2,2′-bipyridyl) dichloride, Tris(2,2′-bipyridyl)ruthenium(II) chloride hexahydrate

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About This Item

Empirical Formula (Hill Notation):
C30H24Cl2N6Ru · 6H2O
CAS Number:
50525-27-4
Molecular Weight:
748.62
MDL number:
MFCD00149670
UNSPSC Code:
12352103
PubChem Substance ID:
24878800
NACRES:
NA.23

Assay

99.95% trace metals basis

mp

>300 °C (lit.)

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2ClH.6H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;;;;;;/h3*1-8H;2*1H;6*1H2;/q;;;;;;;;;;;+2/p-2

InChI key

WHELTKFSBJNBMQ-UHFFFAOYSA-L

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General description

Tris(2,2′-bipyridyl)dichlororuthenium hexahydrate (RTDP, Ru(BPY)3) is an oxygen sensitive fluorescent dye.

Application

RTDP was used to measure the oxygen concentration in a microfluidic chip. A new hybrid material for oxidase based biosensors was prepared by combining Wells–Dawson K7[H4PW18O62]·18H2O (PW18) and RTDP. Silica nanoparticles doped with RTDP render them fluorescent, radio opaque and paramagnetic.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis and Characterization of Fluorescent, Radio-Opaque, and Paramagnetic Silica Nanoparticles for Multimodal Bioimaging Applications
Advanced Materials null
Emily A Seidler et al.
Journal of assisted reproduction and genetics, 37(8), 1797-1805 (2020-08-28)
This study used noninvasive, fluorescence lifetime imaging microscopy (FLIM)-based imaging of NADH and FAD to characterize the metabolic response of mouse embryos to short-term oxygen deprivation. We investigated the response to hypoxia at various preimplantation stages. Mouse oocytes and embryos
Novel organic?inorganic hybrid material based on tris(2,2?-bipyridyl)dichlororuthenium(II) hexahydrate and Dawson-type tungstophosphate K7[H4PW18O62]?18H2O as a bifuctional hydrogen peroxide electrocatalyst for biosensors
Ammam M and Easton EB
Sensors and Actuators B, Chemical null
G L Sharipov et al.
Ultrasonics sonochemistry, 58, 104674-104674 (2019-08-28)
Consideration is given to single and multibubble sonochemiluminescence (SCL) in acidic Ru(bpy)33+ aqueous solutions due to the light emission of the excited ion *Ru(bpy)32+ at 613 nm. Spectrophotometrically controlled reduction of Ru(bpy)33+ to Ru(bpy)32+ occurs in both regimes of sonolysis. The
Novel organic?inorganic hybrid material based on tris(2,2?-bipyridyl)dichlororuthenium(II) hexahydrate and Dawson-type tungstophosphate K7[H4PW18O62]?18H2O as a bifuctional hydrogen peroxide electrocatalyst for biosensors
Ammam M and Easton EB
Sensors and Actuators B, Chemical, 520-527 null
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