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D7766

Sigma-Aldrich

1,5-Diphenylcarbazide

reagent grade

Synonym(s):

1,5-Diphenylcarbohydrazide, sym.-Diphenylcarbazide

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About This Item

Linear Formula:
C6H5NHNHCONHNHC6H5
CAS Number:
140-22-7
Molecular Weight:
242.28
Beilstein:
752039
EC Number:
205-403-7
MDL number:
MFCD00003013
UNSPSC Code:
12352100
PubChem Substance ID:
57654128
NACRES:
NA.21

grade

reagent grade

Quality Level

200

Assay

≥99% (TLC)

form

powder

mp

170-175 °C (lit.)

storage temp.

2-8°C

SMILES string

O=C(NNc1ccccc1)NNc2ccccc2

InChI

1S/C13H14N4O/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14-15H,(H2,16,17,18)

InChI key

KSPIHGBHKVISFI-UHFFFAOYSA-N

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General description

1,5-Diphenylcarbazide (DPC) is a colorimetric reagent commonly employed in the determination of trace metals.

Application

1,5-Diphenylcarbazide may be used in the following processes:
  • Quantification of palladium and platinum by spectrophotometry.
  • As a mediator for the functionalization of carbon paste electrodes employed in the estimation of Hg(II) ions by differential pulse voltammetry.
  • Alteration of gold nanoparticles (AuNPs), employed for the detection of chromium (VI) ions via colorimetry.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000211307
SHBP2521
SHBN9577
SHBN4191
SHBM5246

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Photometric and visual detection of Cr (VI) using gold nanoparticles modified with 1, 5-diphenylcarbazide.
Liu, L, et al.
Microchimica Acta, 1-7 (2016)
Spectrophotometric determination of platinum and palladium with 1, 5-diphenylcarbazide.
Brajter K, et al.
Fresenius Journal of Analytical Chemistry, 328(7), 598-598 (1987)
Kinetic method for the determination of trace amounts of copper (II) in water matrices by its catalytic effect on the oxidation of 1, 5-diphenylcarbazide.
Crespo GA, et al.
Analytica Chimica Acta, 539(1), 317-325 (2005)
Hg (II) voltammetry on a 1, 5-diphenylcarbazide containing carbon paste electrode.
Navratilova Z.
Electroanalysis, 3(8), 799-802 (1991)
A Padarauskas et al.
Journal of chromatography. A, 808(1-2), 193-199 (1998-07-04)
A method for on-line chromatographic preconcentration and determination of chromium(VI) traces has been developed. Chromate was preconcentrated on a C18 column (50 x 6 mm I.D.) after complexation with diphenylcarbazide (DPC). Following the preconcentration step, analysis of the sample was
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