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405647

Sigma-Aldrich

2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone

97%

Synonym(s):

2-(Dimethylamino)-1-(4-morpholinophenyl)-2-benzyl-1-butanone, 2-(Dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-1-butanone, 2-Benzyl-2-dimethylamino-1-(4-morpholinophehyl)-butane-1-one

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About This Item

Empirical Formula (Hill Notation):
C23H30N2O2
CAS Number:
Molecular Weight:
366.50
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Assay

97%

mp

116-119 °C (lit.)

SMILES string

CCC(Cc1ccccc1)(N(C)C)C(=O)c2ccc(cc2)N3CCOCC3

InChI

1S/C23H30N2O2/c1-4-23(24(2)3,18-19-8-6-5-7-9-19)22(26)20-10-12-21(13-11-20)25-14-16-27-17-15-25/h5-13H,4,14-18H2,1-3H3

InChI key

UHFFVFAKEGKNAQ-UHFFFAOYSA-N

General description

2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone (DBMP) is a photoinitiator that acts at near UV and visible range. It can be incorporated into the polymeric matrix, which upon UV irradiation forms radicals by radical chain polymerization.

Application

DBMP can be used as a dopant to dope silicone elastomer for the formation of 3D biocompatible scaffolds. It can also be used in two photon polymerization for the micro-fabrication of 3D hydrogels for potential biomedical and tissue engineering applications.

Pictograms

Health hazardEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

235.4 °F

Flash Point(C)

113 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Three-dimensional laser micro-sculpturing of silicone: towards bio-compatible scaffolds
Rekstyt? S, et al.
Optics Express, 21(14), 17028-17041 (2013)
Yahya Bougdid et al.
Scientific reports, 10(1), 10409-10409 (2020-06-28)
Voxels, the 3D equivalent of 2D pixels, are obtained by individual point exposures in 3D laser nanoprinting, and are the building blocks of laser printed 3D micro/nano-structures, and their optimization is important in determining the resolution of printed 3D objects.
Laser interaction in sol-gel based materials-3-D lithography for photonic applications
Houbertz R
Applied Surface Science, 247(1-4), 504-512 (2005)
Photoinduced free radical promoted copper (I)-catalyzed click chemistry for macromolecular syntheses
Tasdelen MA, et al.
Macromolecules, 45(1), 56-61 (2011)
A water soluble initiator prepared through host-guest chemical interaction for microfabrication of 3D hydrogels via two-photon polymerization
Xing J, et al.
Journal of materials chemistry. B, 2(27), 4318-4323 (2014)

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