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23270

Sigma-Aldrich

Chloramine T trihydrate

purum p.a., for the detection of halogens and bromate, ≥98.0% (RT)

Synonym(s):

N-Chloro-p-toluenesulfonamide sodium salt

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About This Item

Linear Formula:
CH3C6H4SO2NClNa · 3H2O
CAS Number:
Molecular Weight:
281.69
Beilstein:
3924168
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

grade

purum p.a.

Quality Level

Assay

≥98.0% (RT)

quality

for the detection of halogens and bromate

reaction suitability

reagent type: oxidant

mp

167-170 °C (lit.)

SMILES string

O.O.O.Cc1ccc(cc1)S(=O)(=O)N([Na])Cl

InChI

1S/C7H7ClNO2S.Na.3H2O/c1-6-2-4-7(5-3-6)12(10,11)9-8;;;;/h2-5H,1H3;;3*1H2/q-1;+1;;;

InChI key

NZYOAGBNMCVQIV-UHFFFAOYSA-N

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Application

  • Enhancement of Photocatalytic and Antimicrobial Potential: Research into nanocomposites loaded with Chloramine T trihydrate has shown enhanced photocatalytic and antimicrobial properties, suggesting applications in material sciences and environmental engineering (Elkodous et al., 2020).

Other Notes

Review; Oxidizing agent for the preparation of 131I-labeled material with high specific radioactivity; Reagent for the selective oxidation of methionine

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

377.6 °F - closed cup

Flash Point(C)

192 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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The estimation of microgram amounts of methionine by reaction with chloramine-T.
G E Trout
Analytical biochemistry, 93(2), 419-422 (1979-03-01)
Crystal and molecular structure of chloramine-T trihydrate. Absence of a sodium-nitrogen interaction in the oxidant. N-chloro-N-sodiotoluene-p-sulfonamide.
Olmstead MM and Power PP.
Inorganic Chemistry, 25(22), 4057-4058 (1986)
D.H. Bremner
Synthetic Reagents, 6, 9-9 (1985)
Nitrogen atom transfer to alkenes utilizing Chloramine-T as a nitrogen source.
Ando T, et al.
Tetrahedron Letters, 39(3), 309-312 (1998)
M.M. Campbell et al.
Chemical Reviews, 78, 65-65 (1978)

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