跳轉至內容

Design and synthesis of new 1D and 2D R-isophthalic acid-based coordination polymers (R = hydrogen or bromine).

Design and synthesis of new 1D and 2D R-isophthalic acid-based coordination polymers (R = hydrogen or bromine).

Chimia (2013-08-16)

Ren Zhang, Qihan Gong, Thomas J Emge, Debasis Banerjee, Jing Li

摘要

Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.

材料

產品編號

品牌

產品描述

Sigma-Aldrich

溴, ACS reagent, ≥99.5%

Sigma-Aldrich

溴, reagent grade

Sigma-Aldrich

铜, powder, 99.999% trace metals basis

Sigma-Aldrich

铜, foil, thickness 0.25 mm, 99.98% trace metals basis

Sigma-Aldrich

Hydrogen, ≥99.99%

Sigma-Aldrich

铜, powder, <425 μm, 99.5% trace metals basis

Sigma-Aldrich

溴, ≥99.99% trace metals basis

Sigma-Aldrich

间苯二甲酸, 99%

Sigma-Aldrich

铜, wire, diam. 1.0 mm, ≥99.9%

Sigma-Aldrich

铜, powder (spheroidal), 10-25 μm, 98%

Sigma-Aldrich

铜, nanopowder, 40-60 nm particle size (SAXS), ≥99.5% trace metals basis

Sigma-Aldrich

铜, powder, <75 μm, 99%

Sigma-Aldrich

铜, wire, diam. 0.25 mm, 99.999% trace metals basis

Sigma-Aldrich

铜, foil, thickness 0.025 mm, 99.98% trace metals basis

Sigma-Aldrich

铜, nanopowder, 60-80 nm particle size (SAXS), ≥99.5% trace metals basis

Sigma-Aldrich

铜, powder (dendritic), <45 μm, 99.7% trace metals basis

Sigma-Aldrich

铜, foil, ≥99.8% (complexometric)

Sigma-Aldrich

铜, turnings, purum p.a., ≥99.0%

Sigma-Aldrich

铜, foil, thickness 0.5 mm, 99.98% trace metals basis

Sigma-Aldrich

铜, wire, diam. 0.64 mm, 99.995% trace metals basis

Sigma-Aldrich

铜, beads, 2-8 mm, 99.9995% trace metals basis

Sigma-Aldrich

铜, foil, thickness 1.0 mm, 99.999% trace metals basis

Sigma-Aldrich

铜, shot, −3-+14 mesh, 99%

Sigma-Aldrich

铜, wire, diam. 2.0 mm, 99.999% trace metals basis

Sigma-Aldrich

铜, ACS reagent, granular, 10-40 mesh, ≥99.90%

Sigma-Aldrich

铜, beads, 2-8 mm, ≥99.99% trace metals basis

铜 (S, P), BCR^®, certified reference material, chips

铜, IRMM^®, certified reference material, 0.5 mm wire

铜 (O), BCR^®, certified reference material, rod