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Merck
  • Photochemical tuning of light emission in a conjugated polymer containing norbornadiene units in the main chain.

Photochemical tuning of light emission in a conjugated polymer containing norbornadiene units in the main chain.

Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology (2007-04-04)
Francesco Babudri, Gianmarco Bilancia, Antonio Cardone, Paolo Coppo, Luisa De Cola, Gianluca M Farinola, Johannes W Hofstraat, Francesco Naso
摘要

A conjugated alternating copolymer containing norbornadiene and bis(ethynylene)phenylene units was prepared by the Cassar-Heck-Sonogashira cross-coupling reaction. Its electroluminescence was tested in a device, and its fluorescence colour could be tuned by light-induced norbornadiene-quadricyclane isomerization.

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Sigma-Aldrich
双环[2.2.1]庚-2,5-二烯, 98%