- On the relationship between structure and reaction rate in olefin ring-closing metathesis.
On the relationship between structure and reaction rate in olefin ring-closing metathesis.
Chemical communications (Cambridge, England) (2010-09-08)
Ian W Ashworth, Davide Carboni, Ian H Hillier, David J Nelson, Jonathan M Percy, Giuseppe Rinaudo, Mark A Vincent
PMID20820538
摘要
In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic η(2)-complex.
材料