- Room-temperature Hiyama cross-couplings of arylsilanes with alkyl bromides and iodides.
Room-temperature Hiyama cross-couplings of arylsilanes with alkyl bromides and iodides.
Journal of the American Chemical Society (2003-05-08)
Jae-Young Lee, Gregory C Fu
PMID12733884
ABSTRACT
The first method for achieving Hiyama couplings of unactivated alkyl bromides and iodides is reported. The desired carbon-carbon bond formation proceeds under mild conditions (room temperature) with good functional-group tolerance.
MATERIALS