807869

P(o-Tolyl)₃-Pd-G2 GT capsule

• Empirical Formula (Hill Notation): C₃₃H₃₁ClNPPd
• Molecular Weight: 614.45
• MDL number: MFCD22417213
• UNSPSC Code: 12161600
• PubChem Substance ID: 329768751
• NACRES: NA.22

Properties

• form: capsule
• feature: generation 2
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• functional group: phosphine
• InChI: 1S/C21H21P.C12H10N.ClH.Pd/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h4-15H,1-3H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1
• InChI key: MNKLPYUHUVVRNW-UHFFFAOYSA-M

Description

General description

The product is a second generation (G2) Buchwald precatalyst. The G2 precatalysts are improved form of G1 precatalysts. They are formed by substituting the phenethylamine based backbone of the G1 complex with a biphenyl-based ligand. This modification leads to the formation of active Pd species at room temperature with weak bases. Buchwald precatalysts are air, moisture and thermally-stable. It is highly useful in cross-coupling reactions.

Application

Convenient dosable form of P(o-Tolyl)₃-Pd-G2

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable