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221864

Sigma-Aldrich

Potassium bromide

FT-IR grade, ≥99% trace metals basis

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About This Item

Linear Formula:
KBr
CAS Number:
Molecular Weight:
119.00
EC Number:
MDL number:
UNSPSC Code:
12352302
eCl@ss:
38050405
PubChem Substance ID:
NACRES:
NA.21
Assay:
≥99% trace metals basis
grade:
FT-IR grade
form:
powder or crystals
Pricing and availability is not currently available.

grade

FT-IR grade

Quality Level

vapor pressure

<0.01 mmHg ( 20 °C)
1 mmHg ( 795 °C)

Assay

≥99% trace metals basis

form

powder or crystals

technique(s)

FTIR: suitable

pH

5-6 (25 °C, 119 g/L)

mp

734 °C (lit.)

SMILES string

[K+].[Br-]

InChI

1S/BrH.K/h1H;/q;+1/p-1

InChI key

IOLCXVTUBQKXJR-UHFFFAOYSA-M

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General description

Potassium bromide, a water-soluble inorganic salt, is redox reagent.[1]

Application

May be used for removal of peripheral membrane proteins.
Potassium bromide may be used along with:
  • Cerium(IV) ammonium nitrate (CAN) for synthesizing dibromides via alkene bromination.[2]
  • Sodium perborate for synthesizing brominated anilines via oxidative bromination of unprotected aromatic amines.[3]
  • Hydrochloric acid and hydrogen peroxide for the bromination of active methylene and methyne compounds with high chemoselectivity.[4]
Suitable for use with FT-IR spectrometers

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Chemoselective bromination of active methylene and methyne compounds by potassium bromide, hydrochloric acid and hydrogen peroxide.
Shimosaki R, et al.
Synlett, 2006(14), 2287-2289 (2006)
Ville Petteri Heljo et al.
Pharmaceutical research, 28(3), 540-552 (2010-10-23)
The purpose of this study is to show how disaccharides differ in their ability to protect lyophilized β-galactosidase from enzymatic activity loss and secondary structure changes during storage. β-galactosidase was lyophilized with trehalose, sucrose, cellobiose or melibiose at 2:1, 20:1
Mild and regioselective oxidative bromination of anilines using potassium bromide and sodium perborate.
Roche D, et al.
Tetrahedron Letters, 41(13), 2083-2085 (2000)
Madhusmita Dhupal et al.
International journal of nanomedicine, 13, 6735-6750 (2018-11-15)
Titanium dioxide nanoparticles (TiO2 NPs) represent a scientific breakthrough in the areas of biological and medicinal applications. Interaction of TiO2 NPs with components of innate immune system remains elusive. This study explored in vitro immunotoxicity of murine macrophage RAW 264.7
An efficient bromination of alkenes using cerium (IV) ammonium nitrate (CAN) and potassium bromide.
Nair V, et al.
Tetrahedron, 57(34), 7417-7422 (2001)

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Dear Sr, I want to confirm if the product: https://www.sigmaaldrich.com/AR/es/product/sigald/221864 is suitable for FTIR spectroscopy

    1 answer
    1. Yes. This product is suitable for FT-IR spectroscopy.

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