216828

Iron(III) nitrate nonahydrate

ACS reagent, ≥98%

• Synonym(s): Ferric nitrate nonahydrate
• Linear Formula: Fe(NO₃)₃ · 9H₂O
• CAS Number: 7782-61-8
• Molecular Weight: 404.00
• EC Number: 233-899-5
• MDL number: MFCD00149708
• UNSPSC Code: 12352302
• PubChem Substance ID: 329752193
• NACRES: NA.21

Properties

• grade: ACS reagent
• Assay: ≥98%; 98.0-101.0% (ACS specification)
• form: moist crystals
• reaction suitability: reagent type: catalyst; core: iron
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• impurities: ≤0.005% insolubles; ≤0.1% Substances not pptd. by NH₄OH (as sulfates)
• pH: 1.5 (20 °C)
• mp: 47 °C (lit.)
• anion traces: chloride (Cl^-): ≤5 ppm; sulfate (SO₄^2-): ≤0.01%
• cation traces: Ca: ≤0.01%; K: ≤0.005%; Mg: ≤0.005%; Na: ≤0.05%
• greener alternative category: , Aligned
• SMILES string: O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
• InChI: 1S/Fe.3NO3.9H2O/c;3*2-1(3)4;;;;;;;;;/h;;;;9*1H2/q+3;3*-1;;;;;;;;;
• InChI key: SZQUEWJRBJDHSM-UHFFFAOYSA-N

Description

General description

Iron(III) nitrate nonahydrate is an inorganic iron salt that is used as an iron precursor for the synthesis of iron oxide nanoparticles.

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Application

A variety of organically templated iron phosphates, of interest because of their rich crystal chemistry and their ability to absorb large molecules in their micropores,were prepared using this compound.

Iron(III) nitrate nonahydrate can be used as:     

• A catalyst in the oxidation of 1^o, 2^o, and benzylic alcohols to their corresponding carbonyl compounds in the presence of heteropoly acids.      
• A promoter in the synthesis of polycrystalline boron nitride nanotubes (BNNTs) by a ball milling-annealing method.

It can also be used to synthesize:      

• Iron-doped mesoporous silica used as an efficient catalyst for the degradation of rhodamine B dye under acidic conditions.
• Iron(III)-doped titania nanoparticles by modified sol-gel method.

Safety Information

• Pictograms: GHS05
• Signal Word: Danger
• Hazard Statements: H314
• Precautionary Statements: P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Storage Class Code: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable